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477400

Sigma-Aldrich

(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)

97%

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About This Item

Linear Formula:
[(C6H5)3P]2Re(CH3CN)Cl3
CAS Number:
34387-57-0
Molecular Weight:
858.19
MDL number:
MFCD01863511
UNSPSC Code:
12352300
PubChem Substance ID:
24871368

Assay

97%

reaction suitability

core: rhenium
reagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

CC#N.Cl[Re](Cl)Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.C2H3N.3ClH.Re/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-3;;;;/h2*1-15H;1H3;3*1H;/q;;;;;;+3/p-3

InChI key

SEHZOVVCPGBXNW-UHFFFAOYSA-K

Application

Catalyst for addition of tetrahalomethanes to alkenes and 1-omega-dienes

Reactant for synthesis of:
  • Re(III) complexes containing 2-benzoylpyridine
  • Rhenium(IV) and (V) complexes
  • Rhenium triphosphorus macrocycle complexes and reactions with alkenes

Reactant for rhenium chemistry of azooximes

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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