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36818

Sigma-Aldrich

Diethylenetriaminepentakis(methylphosphonic acid) solution

technical, ~50% (T)

Synonym(s):

Diethylenetriamine-N,N,N′,N′′,N′′-penta(methylenephosphonic acid), Diethylenetriamine-N,N,N′,N′′,N′′-pentakis(methylenephosphonic acid), Diethylenetriaminepenta(methylenephosphonic acid), Diethylenetriaminopenta(methylenephosphonic acid), Ethylenetriaminepenta(methylenephosphonic acid), P,P′,P′′,P′′′-[[(Phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis[phosphonic acid]

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About This Item

Empirical Formula (Hill Notation):
C9H28N3O15P5
CAS Number:
15827-60-8
Molecular Weight:
573.20
Beilstein:
2068968
MDL number:
MFCD00129718
UNSPSC Code:
12352100
PubChem Substance ID:
57649668
NACRES:
NA.22

grade

technical

form

liquid

composition

HCl, 15%
H2O, ~35%

concentration

~50% (T)

SMILES string

OP(O)(=O)CN(CCN(CP(O)(O)=O)CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O

InChI

1S/C9H28N3O15P5/c13-28(14,15)5-10(1-3-11(6-29(16,17)18)7-30(19,20)21)2-4-12(8-31(22,23)24)9-32(25,26)27/h1-9H2,(H2,13,14,15)(H2,16,17,18)(H2,19,20,21)(H2,22,23,24)(H2,25,26,27)

InChI key

DUYCTCQXNHFCSJ-UHFFFAOYSA-N

General description

Diethylenetriaminepentakis(methylphosphonic acid) (DTPMP) is a multidentate chelating agent. Hydrogen peroxide oxidation of DTPMP is reported. DTPMP, a phosphonate, is commonly used as crystallization inhibitors.

Application

Diethylenetriaminepentakis(methylphosphonic acid) solution is suitable for use in a study to investigate the dynamics and kinetics of sodium sulfate crystallization in the presence of various organophosphonic acids. It may be employed as ligand for the characterization of Ce3+ complexes by luminescence spectroscopy.

Other Notes

Multidentate complexing agent

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290,H315,H318,H335

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Mika Sillanpää et al.
Archives of environmental contamination and toxicology, 44(3), 332-335 (2003-04-25)
Acute toxicity of four relatively new chelating agents and their equimolar manganese and cadmium complexes was studied. The chelating agents studied were gluconic acid (GA), beta-alaninediacetic acid (ADA), diethylenetriaminepentakismethylenephosphonic acid (DTPMP), and nitrilotriacetic acid (NTA). Three common bioassays, namely Daphnia
M Láznícek et al.
Nuclear medicine communications, 17(12), 1016-1020 (1996-12-01)
The distribution and elimination of 99Tcm-complexes with methylene-diphosphonate (MDP) and with the calcium salt of diethylene-triamine-penta(methylene phosphonate) (DTPMP) were compared in rats. Both compounds exhibited high bone uptake and long-term retention of radioactivity in the skeleton. No significant accumulation of
Complexation, luminescence, and energy transfer of cerium (3+) with a series of multidentate aminophosphonic acids in aqueous solution.
Frey ST and Horrocks Jr WD.
Inorganic Chemistry, 30(5), 1073-1079 (1991)
Sodium sulfate crystallization in the presence of phosphonates: Implications in ornamental stone conservation.
Ruiz-Agudo E, et al.
Crystal Growth & Design, 6(7), 1575-1583 (2006)
M.B. Tomson et al.
Langmuir, 10, 1442-1442 (1994)
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