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About This Item
Linear Formula:
[-CH2CH(Br)CO2C2H5]2
CAS Number:
Molecular Weight:
360.04
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
mp
65-67 °C (lit.)
SMILES string
CCOC(=O)[C@@H](Br)CC[C@@H](Br)C(=O)OCC
InChI
1S/C10H16Br2O4/c1-3-15-9(13)7(11)5-6-8(12)10(14)16-4-2/h7-8H,3-6H2,1-2H3/t7-,8+
InChI key
UBCNJHBDCUBIPB-OCAPTIKFSA-N
Related Categories
General description
Diethyl meso-2,5-dibromoadipate reacts with N-methylallylamine in the presence of potassium carbonate to yield two diastereomers of diethyl 2-allyl-N-methylpyrrolidine-2,5-dicarboxylate.
Application
Diethyl meso-2,5-dibromoadipate may be employed as difunctional initiator during n-butyl acrylate (n-BuA) polymerization, leading to α,ω-bromo-poly(n-BuA) having narrow molecular weight distribution. It was also used:
- as bifunctional atom transfer radical polymerization (ATRP) initiator
- as initiator during the solution polymerization of octadecyl ester ether dimer by ATRP
- in the synthesis of diethyl 2,5-diazidoadipate
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Find documentation for the products that you have recently purchased in the Document Library.
Effect of Block Order of ABA-and BAB-Type NIPAAm/HEMA Triblock Copolymers on Thermoresponsive Behavior of Solutions.
Zhao X, et al.
Macromolecular Chemistry and Physics, 208(16), 1773-1781 (2007)
GRAFTING CARBOXYLIC ACIDS AND TERTIARY AMINES ONTO AZIDE-CONTAINING ALIPHATIC POLYESTERS.
Brown AH and Sheares VV.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 49(1), 181-181 (2008)
Tandem cyclisation and [2, 3]-Stevens rearrangement to 2-substituted pyrrolidines.
Smith SC and Bentley PD.
Tetrahedron Letters, 43(5), 899-902 (2002)
ATOM TRANSFER RADICAL POLYMERIZATION OF OCTADECYL a-(HYDROXYMETHYL) ACRYLATE ESTER ETHER DIMER AND THEIR CORRESPONDING BLOCK COPOLYMERS.
Ozkal E, et al.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 49(1), 416-416 (2008)
Controlled radical polymerization of (meth) acrylates by ATRP with NiBr2 (PPh3) 2 as catalyst.
Moineau G, et al.
Macromolecules, 32(1), 27-35 (1999)
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