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340286

Sigma-Aldrich

Dimethyl methylmalonate

99%

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About This Item

Linear Formula:
CH3CH(CO2CH3)2
CAS Number:
609-02-9
Molecular Weight:
146.14
EC Number:
210-173-6
MDL number:
MFCD00075185
UNSPSC Code:
12352100
PubChem Substance ID:
24860790

vapor pressure

0.2 mmHg ( 20 °C)

Assay

99%

refractive index

n20/D 1.414 (lit.)

bp

176-177 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

SMILES string

COC(=O)C(C)C(=O)OC

InChI

1S/C6H10O4/c1-4(5(7)9-2)6(8)10-3/h4H,1-3H3

InChI key

LRBPFPZTIZSOGG-UHFFFAOYSA-N

General description

Dimethyl methylmalonate is an ester. Microwave-enhanced Pd(0)/acetic acid catalyzed allylation of C, N and O-nucleophiles with dimethyl methylmalonate has been reported.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

168.8 °F - closed cup

Flash Point(C)

76 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
18404LR
11507DZ
04105KV
20204LR
07420PY

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Microwave-enhanced Pd (0)/acetic acid catalyzed allylation reactions of C, N, and O -pronucleophiles with alkynes.
Patil NT, et al.
Tetrahedron Letters, 45(46), 8497-8499 (2004)

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