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About This Item
Linear Formula:
NH2COOCH3
CAS Number:
Molecular Weight:
75.07
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
crystals
bp
176-177 °C (lit.)
mp
56-58 °C (lit.)
solubility
alcohol: freely soluble(lit.)
water: freely soluble(lit.)
functional group
amine
SMILES string
COC(N)=O
InChI
1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)
InChI key
GTCAXTIRRLKXRU-UHFFFAOYSA-N
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Related Categories
Application
Methyl carbamate was used in the synthesis of protected aminocyclopropanes[1].
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
Methyl carbamate: negative results in mouse bone-marrow micronucleus test.
M D Shelby et al.
Mutation research, 260(4), 311-311 (1991-08-01)
Genotoxicity data supporting the proposed metabolic activation of ethyl carbamate (urethane) to a carcinogen: the problem now posed by methyl carbamate.
J Ashby
Mutation research, 260(4), 307-308 (1991-08-01)
R G Ames et al.
Archives of environmental health, 50(6), 440-444 (1995-11-01)
To test the hypothesis that chronic neurologic sequelae are associated with cholinesterase depression short of frank organophosphate poisoning, we compared 45 male subjects who had a history of moderate cholinesterase inhibition with 90 male subjects who had neither past cholinesterase
N P Sen et al.
Food additives and contaminants, 9(2), 149-160 (1992-03-01)
A method is described for the simultaneous determination of methyl carbamate (MC) and ethyl carbamate (EC) in wines that is based on: (a) extraction of the sample with dichloromethane using an extraction tube or an alumina-Celite column, (b) concentration of
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