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Sigma-Aldrich

Sodium cyanide

Sodium cyanide

ACS reagent, ≥95.0%

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About This Item

Linear Formula:
NaCN
CAS Number:
Molecular Weight:
49.01
Beilstein:
3587243
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NB.24
Assay:
≥95.0%
grade:
ACS reagent
form:
crystalline powder
powder, crystals or chunks
solubility:
water: soluble(lit.)
Pricing and availability is not currently available.

grade

ACS reagent

Quality Level

vapor density

1.7 (vs air)

vapor pressure

1 mmHg ( 817 °C)

Assay

≥95.0%

form

crystalline powder
powder, crystals or chunks

pH

11-12 (25 °C, 49 g/L)

mp

563.7 °C (lit.)

solubility

water: soluble(lit.)

anion traces

S2-: ≤0.005%
SCN-: ≤0.02%
chloride (Cl-): ≤0.15%
phosphate (PO43-): ≤0.02%
sulfate (SO42-): ≤0.05%

cation traces

Fe: ≤0.005%
Pb: ≤0.005%

SMILES string

[Na]C#N

InChI

1S/CN.Na/c1-2;

InChI key

RTVFYQXEHKQMKO-UHFFFAOYSA-N

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General description

Sodium cyanide is colorless sodium salt and its crystals belong to the cubic crystal system. Its aqueous solutions are strongly basic due to the presence of cyanide ion. It can be synthesized by reacting sodium hydroxide with hydrogen cyanide. Sodium cyanide is a key precursor for the synthesis of various organic intermediates.[1] It participates in the RuCl3-mediated oxidative cyanation of tertiary amines.[2]

Application

Sodium cyanide may be employed for the synthesis of the following compounds:
  • α-amino acids[3]
  • Prussian blue (cyanide pigment)[1]
  • nitriles, via reaction with primary and secondary chlorides[4]

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 1 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 1

Target Organs

Thyroid

Supplementary Hazards

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3


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Daniela Gontero et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 19(9), 1168-1188 (2020-07-18)
Escherichia coli bacteria were determined by in flow cytometry with laser excitation and fluorescence detection applying ultraluminescent core-shell nanoparticles based on Metal Enhanced Fluorescence (MEF). Core-shell nanoparticles consisted of a 40 nm core modified with a silica spacer grafted with
Eagleson M.
Concise Encyclopedia Chemistry, 1037-1037 (1994)
Preparation of Nitriles from Halides and Sodium Cyanide. An Advantageous Nucleophilic Displacement in Dimethyl Sulfoxide1a.
Friedman L and Shechter H.
The Journal of Organic Chemistry, 25(6), 877-879 (1960)
Shun-Ichi Murahashi et al.
Journal of the American Chemical Society, 125(50), 15312-15313 (2003-12-11)
RuCl3-catalyzed oxidative cyanation of tertiary amines with sodium cyanide under molecular oxygen (1 atm) at 60 degrees C gives the corresponding alpha-aminonitriles, which are versatile synthetic intermediates of various compounds such as amino acids and unsymmetrical 1,2-diamines, in excellent yields.
Jian Tan et al.
Molecular vision, 17, 3300-3308 (2011-12-24)
Loss of retinal ganglion cells (RGCs) during retinal ischemia is the potentially blinding mechanism that underlies several sight-threatening disorders. Fluctuations in extracellular pH are associated with such pathological conditions. It has been demonstrated that the retina is a functionally distinct

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