751413
Di(1-adamantyl)-2-dimethylaminophenylphosphine
98%
Synonym(s):
2-(Di-1-adamantylphosphino)-N,N-dimethylaniline, 2-(Di-1-adamantylphosphino)dimethylaminobenzene, 2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine, Me-Dalphos
About This Item
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Quality Level
Assay
98%
form
solid
reaction suitability
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
mp
237-242 °C
functional group
phosphine
SMILES string
CN(C)c1ccccc1P([C@@]23C[C@@H]4C[C@@H](C[C@@H](C4)C2)C3)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
InChI
1S/C28H40NP/c1-29(2)25-5-3-4-6-26(25)30(27-13-19-7-20(14-27)9-21(8-19)15-27)28-16-22-10-23(17-28)12-24(11-22)18-28/h3-6,19-24H,7-18H2,1-2H3/t19-,20+,21-,22-,23+,24-,27-,28-
InChI key
MILNYLCUWRWYBI-XMCXLQRDSA-N
Related Categories
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Articles
DalPhos ligands enable Pd-catalyzed C-N and C-C bond formation with good functional group tolerance.
DalPhos ligands enable Pd-catalyzed C-N and C-C bond formation with good functional group tolerance.
DalPhos ligands enable Pd-catalyzed C-N and C-C bond formation with good functional group tolerance.
DalPhos ligands enable Pd-catalyzed C-N and C-C bond formation with good functional group tolerance.
Related Content
The main focus of the Stradiotto group has centered on the development and application of novel electronically rich, sterically encumbered P,N-based ancillary ligands for use in late metal catalysis, including Pd and Au chemistry.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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