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736414

Sigma-Aldrich

Tetradecylphosphonic acid

98%

Synonym(s):

TDPA, TPA

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About This Item

Linear Formula:
CH3(CH2)13P(O)(OH)2
CAS Number:
4671-75-4
Molecular Weight:
278.37
EC Number:
225-118-1
MDL number:
MFCD00015834
UNSPSC Code:
12352300
PubChem Substance ID:
329765108
NACRES:
NA.23

Assay

98%

form

solid

mp

80-85 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCCCP(O)(O)=O

InChI

1S/C14H31O3P/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-18(15,16)17/h2-14H2,1H3,(H2,15,16,17)

InChI key

BVQJQTMSTANITJ-UHFFFAOYSA-N

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General description

Tetradecylphosphonic acid forms a self-assembled monolayer (SAM) to functionalize a variety of nanoparticles.

Application

TDPA can be used to cap copper nanoparticles to protect them from oxidation. It may also be used in the synthesis of cadmium sulfate (CdS) core, which can be used in the fabrication of cadmium selenium (CdSe)/CdS core quantum dots (QDs). It may also be coated on caesium lead bromide (CsPbBr3) perovskite quantum dots for the development of white light emitting diodes (wLED).

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Tailoring Morphology of Cu-Ag Nanocrescents and Core-Shell Nanocrystals Guided by a Thermodynamic Model
Osowiecki WT, et al.
Journal of the American Chemical Society (2018)
Highly stable CsPbBr 3 quantum dots coated with alkyl phosphate for white light-emitting diodes
Xuan T, et al.
Nanoscale, 9(40), 15286-15290 (2017)
Stencil lithography for organic thin-film transistors with a channel length of 300 nm
Zschieschang U, et al.
Organic Electronics, 61, 65-69 (2018)
Lan Yang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(7), e1906766-e1906766 (2020-01-28)
Herein, the facile preparation of ultrathin (≈3.8 nm in thickness) 2D cobalt phosphate (CoPi) nanoflakes through an oil-phase method is reported. The obtained nanoflakes are composed of highly ordered mesoporous (≈3.74 nm in diameter) structure and exhibit an amorphous nature.
Effects of shell thickness on the electric field dependence of exciton recombination in CdSe/CdS core/shell quantum dots
Rowland CE, et al.
Optical Materials Express, 7(6), 1871-1881 (2017)
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