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Key Documents

G307

Sigma-Aldrich

Galvinoxyl, free radical

Synonyme(s) :

2,6-Di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy, free radical

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About This Item

Formule empirique (notation de Hill):
C29H41O2
Numéro CAS:
Poids moléculaire :
421.63
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352000
ID de substance PubChem :
Nomenclature NACRES :
NA.22

Pf

158-159 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

CC(C)(C)c1cc(\C=C2\C=C(C(=O)C(=C2)C(C)(C)C)C(C)(C)C)cc(c1[O])C(C)(C)C

InChI

1S/C29H41O2/c1-26(2,3)20-14-18(15-21(24(20)30)27(4,5)6)13-19-16-22(28(7,8)9)25(31)23(17-19)29(10,11)12/h13-17H,1-12H3

Clé InChI

GNZDAXRYGVFYPU-UHFFFAOYSA-N

Application

Free radical and free-radical scavenger.

Code de la classe de stockage

11 - Combustible Solids

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Lan-Fen Wang et al.
Bioorganic chemistry, 33(2), 108-115 (2005-03-25)
To improve the radical-scavenging activity of catechin, a planar catechin analogue was designed and synthesized by Fukuhara [J. Am. Chem. Soc. 124 (2002) 5952]. Although the planar catechin is less active than quercetin, it is much more active than catechin
Shuichi Shimakawa et al.
Lipids, 38(3), 225-231 (2003-06-06)
Nitroxyl radicals are known to act as radical scavenging antioxidants. In the present study, a lipophilic nitroxyl radical, cyclohexane-1-spiro-2'-(4'-oxyimidazolidine-1'-oxyl)-5'-spiro-1"-cyclohexane (nitroxyl radical I) was synthesized and its antioxidant capacity was assessed in comparison with a hydrophilic nitroxyl radical, 4-hydroxy-2,2,6,6-tetra-methylpiperidine-N-oxyl (Tempol). Both
Jun Takebayashi et al.
Biological & pharmaceutical bulletin, 29(4), 766-771 (2006-04-06)
The aim of this study was to characterize the antioxidant activity of three ascorbic acid (AA) derivatives O-substituted at the C-2 position of AA: ascorbic acid 2-glucoside (AA-2G), ascorbic acid 2-phosphate (AA-2P), and ascorbic acid 2-sulfate (AA-2S). The radical-scavenging activities
Mónica Espinoza et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(5), 1638-1643 (2008-08-05)
Four different types of Chilean wines (Cabernet Sauvignon, Merlot, Carmenere and Syrah) were selected and examined in their free radical scavenging capacities by electron spin resonance (ESR) and spectrophotometric methods. The free radical scavenging properties were evaluated against 2,2-diphenyl-1-picrylhydrazyl (DPPH*)
Yang Yang et al.
Free radical research, 45(4), 445-453 (2010-12-07)
Cinnamoylphenethylamine (CNPA) derivatives including feruloylphenethylamine (FRPA), caffeoylphenethylamine (CFPA), cinnamoyltyramine (CNTA), feruloyltyramine (FRTA) and caffeoyltyramine (CFTA) were synthesized in order to investigate the influence of the number and position of hydroxyl group on Cu(2+)/glutathione (GSH) and 2,2'-azobis(2-amidinopropane hydrochloride) (AAPH)-induced oxidation of

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