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Principaux documents

43961

Sigma-Aldrich

1-Allyl-3-methylimidazolium chloride

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≥97.0% (HPLC)

Synonyme(s) :

AMIM-Cl

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About This Item

Formule empirique (notation de Hill):
C7H11ClN2
Numéro CAS:
Poids moléculaire :
158.63
Numéro MDL:
Code UNSPSC :
12352100
ID de substance PubChem :
Nomenclature NACRES :
NA.22
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Niveau de qualité

Essai

≥97.0% (HPLC)

Forme

crystals

Caractéristiques du produit alternatif plus écologique

Safer Solvents and Auxiliaries
Catalysis
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Température de stockage

−20°C

Chaîne SMILES 

[Cl-].C[n+]1ccn(CC=C)c1

InChI

1S/C7H11N2.ClH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1

Clé InChI

QVRCRKLLQYOIKY-UHFFFAOYSA-M

Description générale

1-Allyl-3-methylimidazolium chloride is a thermostable and nonvolatile[1] task-specific ionic liquid (TSIL). It shows high cellulose solubilization ability.[2]
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Application

AMIM-Cl may be used:
  • As a solvent to dissolve cellulose during the preparation of regenerated cellulose materials.[1]
  • As a solvent for the acetylation of cornhusk cellulose to form cornhusk cellulose acetates (CCAs).[3]
  • As a plasticizer for cornstarch to form AMIM-Cl-plasticized starch film.[4]

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves


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Consulter la Bibliothèque de documents

Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl).
Cao Y, et al.
Carbohydrate Polymers, 69(4), 665-672 (2007)
Ganeswar Sahu et al.
Polymers, 12(2) (2020-02-13)
This paper presents the dielectric characteristics of nanocomposite films of poly(vinyl alcohol) (PVA) embedded with silver (Ag) nanoparticles and graphene oxide(GO). The nanocomposite films were fabricated by using the solvent casting approach. The morphological analysis was carried out through scanning
Ashna Rajeev et al.
Soft matter, 14(37), 7615-7624 (2018-08-31)
Water added to a solution of microcrystalline cellulose (MCC) in 1-allyl-3-methylimidazolium chloride (AmimCl) reduces the solvent quality and causes significant changes in the flow properties and microstructure due to restructuring and aggregation of cellulose molecules. We report an experimental investigation
Tosylation and acylation of cellulose in 1-allyl-3-methylimidazolium chloride.
Granstrom M, et al.
Cellulose, 15(3), 481-488 (2008)
T Alexandra Ferreira et al.
Molecules (Basel, Switzerland), 24(3) (2019-01-27)
In this work, a procedure using solid phase microextraction in combination with capillary electrophoresis was developed for the determination of oxytetracycline in milk samples. The method involves the synthesis of poly(1-allyl-3-methyl imidazolium) chloride film on a stainless-steel bar via electropolymerization

Articles

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

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