Accéder au contenu
Merck
Toutes les photos(1)

Key Documents

View All Documentation

372439

Sigma-Aldrich

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Synonyme(s) :

Heptadecafluorodecahydro(trifluoromethyl)naphthalene

Se connecterpour consulter vos tarifs contractuels et ceux de votre entreprise/organisme
Toutes les photos(1)

About This Item

Formule empirique (notation de Hill):
C11F20
Numéro CAS:
51294-16-7
Poids moléculaire :
512.09
Code UNSPSC :
12352100
ID de substance PubChem :
24863035
Nomenclature NACRES :
NA.22

Qualité

technical grade

Pureté

80%

Forme

liquid

Indice de réfraction

n20/D 1.317 (lit.)

Point d'ébullition

137-160 °C (lit.)

Pf

−40 °C (lit.)

Densité

1.95 g/mL at 25 °C (lit.)

Chaîne SMILES 

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31

Clé InChI

LWRNQOBXRHWPGE-UHFFFAOYSA-N

Description générale

Perfluoro(methyldecalin) is a fluorinated solvent.

Application

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol). It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi). Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.

Autres remarques

Contains perfluorodecalin

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

235.0 °F - closed cup

Point d'éclair (°C)

112.80 °C - closed cup

Équipement de protection individuelle

Eyeshields, Gloves

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

Déjà en possession de ce produit ?

Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Les clients ont également consulté

Slide 1 of 4

1 of 4

Octafluoronaphthalene 96%

Sigma-Aldrich

248061

Octafluoronaphthalene

Heptacosafluorotributylamine analytical standard, suitable for mass spectrometry (MS)

Supelco

77299

Heptacosafluorotributylamine

Tetradecafluorohexane 99%

Sigma-Aldrich

281042

Tetradecafluorohexane

Ethyl alcohol, Pure 200 proof, ACS reagent, ≥99.5%

Sigma-Aldrich

459844

Ethyl alcohol, Pure

M K Bakulin et al.
Prikladnaia biokhimiia i mikrobiologiia, 43(4), 443-449 (2007-10-13)
The addition of perfluorocarbons (perfluorodecalin, carbogal, and perfluoromethyldecalin) to nitrogen-free liquid media during the submerged cultivation of bacteria of the genus Azotobacter was followed by (1) increases in biomass accumulation and nitrogenase activity and (2) fixation of molecular nitrogen. Addition
37. Polycyclic fluoroaromatic compounds. Part II. Perfluoromethylnaphthalenes and derived compounds.
Gething B, et al.
Journal of the Chemical Society, 190-193 (1962)
D J McIver et al.
Biochimica et biophysica acta, 751(1), 74-80 (1983-03-22)
An effective substitute for pulmonary surfactant must be able to reduce water-vapour surface tensions to under 1 mN/m and it must spread rapidly and spontaneously at the air interface from the aqueous phase. Pure dipalmitoylphosphatidylcholine meets the former requirement, but
Perfluoro-1-methyldecalin as a potential oxygen carrier with fluid scleral lenses.
M F Refojo et al.
Current eye research, 4(6), 732-733 (1985-06-01)
Vasily N Korotchenko et al.
Organic & biomolecular chemistry, 6(11), 1961-1965 (2008-05-16)
Carbonylruthenium tetrakis(pentafluorophenyl)porphyrin Ru(TPFPP)(CO) was utilized for the aerobic oxidation of alcohols. The in situ activation of the catalyst with mCPBA provided a species capable of catalyzing the oxidation of alcohols with molecular oxygen. The choice of solvent and additive was
Afficher tous les articles scientifiques apparentés

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

Contacter notre Service technique