177261

DPPF

97%

• Synonyme(s) : 1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf
• Formule empirique (notation de Hill): C₃₄H₂₈FeP₂
• Numéro CAS: 12150-46-8
• Poids moléculaire : 554.38
• Numéro MDL: MFCD00001422
• Code UNSPSC : 12350000
• ID de substance PubChem : 24850625
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 97%
• Forme: powder
• Capacité de réaction: reaction type: Cross Couplings
• Pertinence de la réaction: reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: ligand; reaction type: Carbonylations; reagent type: ligand; reaction type: Ene Reaction; reagent type: ligand; reaction type: Heck Reaction; reagent type: ligand; reaction type: Negishi Coupling; reagent type: ligand; reaction type: Sonogashira Coupling; reagent type: ligand; reaction type: Stille Coupling; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Tsuji-Trost Reaction
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Pf: 181-182 °C (dec.) (lit.)
• Groupe fonctionnel: phosphine
• Autre catégorie plus écologique: Aligned,
• Chaîne SMILES: [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
• Clé InChI: HPXNTHKXCYMIJL-UHFFFAOYSA-N

Description

Description générale

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)