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D4630

Sigma-Aldrich

2,5-Diphenyloxazole

suitable for liquid scintillation spectrometry

Synonym(s):

DPO, PPO

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About This Item

Empirical Formula (Hill Notation):
C15H11NO
CAS Number:
Molecular Weight:
221.25
Beilstein:
157021
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

form

powder

bp

360 °C (lit.)

mp

72-74 °C (lit.)

suitability

suitable for liquid scintillation spectrometry

SMILES string

c1ccc(cc1)-c2cnc(o2)-c3ccccc3

InChI

1S/C15H11NO/c1-3-7-12(8-4-1)14-11-16-15(17-14)13-9-5-2-6-10-13/h1-11H

InChI key

CNRNYORZJGVOSY-UHFFFAOYSA-N

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General description

2,5-Diphenyloxazole (also known as PPO or p-phenylphenoxazole) is a fluorescent organic compound. It can be also used as an organic scintillator due to its high photoluminescence quantum yield and intriguing luminescent properties. It is widely used as a fluorescent probe or dye in analytical chemistry and biochemistry.

Application

2,5-Diphenyloxazole (PPO) can be used in:
  • fluorography techniques for the detection of tritium, tritiated glycopeptides, and 35S labeled proteins.
  • liquid scintillation cocktails as primary and secondary fluors.

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

386.6 - 393.8 °F - closed cup

Flash Point(C)

197 - 201 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Wavelength dependant quenching of 2, 5-diphenyloxazole fluorescence by nucleotides
KrishnaMurthy NV, et al.
Journal of Fluorescence, 18, 29-34 (2008)
Study of new luminophores for use in modern scintillation cocktails
Janda J, et al.
Journal of Luminescence, 201, 390-396 (2018)
Two-component molecular materials of 2, 5-diphenyloxazole exhibiting tunable ultraviolet/blue polarized emission, pump-enhanced luminescence, and mechanochromic response
Yan, et al.
Advanced Functional Materials , 24, 587-594 (2014)
H J Meyer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 6(15), 2809-2817 (2000-09-14)
Spectral and time-resolved fluorescence properties as well as relative fluorescence quantum yields of carbodiimide derivatives of 2.5-diphenyloxazole (PPO) (prepared by H2S elimination from the corresponding thioureas), of some intermediates in the preparation, and of several other PPO derivatives were investigated
Olivier Braem et al.
Physical chemistry chemical physics : PCCP, 14(10), 3513-3519 (2012-02-07)
We present a femtosecond broad-band fluorescence up-conversion study of the vibrational relaxation dynamics of two UV chromophores, 2,5-diphenyloxazole (PPO) and para-terphenyl (pTP), pumped with a large excess of vibrational energy (>2000 cm(-1)). The band narrowing of the transient fluorescence spectrum

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