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73059

Sigma-Aldrich

Potassium thiocyanate solution

volumetric, 8 M KSCN

Synonym(s):

Potassium rhodanide

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About This Item

Linear Formula:
KSCN
CAS Number:
Molecular Weight:
97.18
Beilstein:
3594799
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.26

product line

BioUltra

Quality Level

form

liquid

quality

volumetric

concentration

8 M KSCN

impurities

insoluble matter, passes filter test

pH

6-11 (25 °C, 8 M in H2O)

solubility

H2O: 8 M at 20 °C, clear, colorless

density

1.342 g/mL at 20 °C
1 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg
sulfide (S2-): ≤20 mg/kg

cation traces

Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤10 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
NH4+: ≤10 mg/kg
Na: ≤200 mg/kg
Ni: ≤1 mg/kg
Pb: ≤2 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

absorption

cut-off at 274 nm in H2O at 8 M

SMILES string

[K+].[N-]=C=S

InChI

1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1

InChI key

ZNNZYHKDIALBAK-UHFFFAOYSA-M

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Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1

Supplementary Hazards

Storage Class Code

12 - Non Combustible Liquids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Katie V Farrant et al.
Journal of bacteriology, 203(2) (2020-10-28)
Pseudomonas aeruginosa is a significant nosocomial pathogen and is associated with lung infections in cystic fibrosis (CF). Once established, P. aeruginosa infections persist and are rarely eradicated despite host immune cells producing antimicrobial oxidants, including hypochlorous acid (HOCl) and hypothiocyanous
A Botti et al.
The journal of physical chemistry. B, 113(29), 10014-10021 (2009-07-03)
The results of a neutron diffraction experiment performed on aqueous solutions of KSCN are analyzed and discussed in comparison with similar data for KCl and KOH solutions. The effect of the different ions on the structure of water and the
Fei Wang et al.
The Journal of organic chemistry, 77(8), 4148-4151 (2012-03-27)
A concise approach to various benzisothiazol-3(2H)-one derivatives has been developed by copper-catalyzed the reaction of o-bromobenzamide derivatives with potassium thiocyanate (KSCN) in water. The reaction proceeds via a tandem reaction with S-C bond and S-N bond formation.
Hongtao Bian et al.
The journal of physical chemistry. B, 116(49), 14426-14432 (2012-11-28)
Microscopic structures and dynamics of aqueous salt solutions were investigated with the ultrafast vibrational energy exchange method and anisotropy measurements. In KSCN aqueous solutions of various concentrations, the rotational time constants of SCN(-) anions are proportional to the viscosities of
Altamir Benedito de Sousa et al.
Reproductive toxicology (Elmsford, N.Y.), 23(4), 568-577 (2007-03-06)
A study was performed at term and at weaning to verify the toxic effects of the prenatal exposure to potassium cyanide (KCN) and potassium thiocyanate (KSCN) in pregnant Wistar rats. Females received daily in drinking water the doses: 1, 3

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