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One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent.

ChemSusChem (2012-11-28)
Pei Huang, Min Wu, Shigenori Kuga, Deqian Wang, Dayong Wu, Yong Huang
RÉSUMÉ

Got a crush: Native cellulose can be dispersed as nanofibers in organic solvents by ball milling with esterification agents. Milling with hexanoyl chloride/DMF gives hexanoyl-coated nanofibers dispersible in several organic solvents. Milling with succinic anhydride/DMSO results water-dispersible nanofibers. The results open the way to new cellulose mechanochemistries.

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Sigma-Aldrich
N,N-Diméthylformamide, ACS reagent, ≥99.8%
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N,N-Diméthylformamide, suitable for HPLC, ≥99.9%
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N,N-Diméthylformamide, anhydrous, 99.8%
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N,N-Diméthylformamide, suitable for HPLC, ≥99.9%
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Sigma-Aldrich
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