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34850-M

Sigma-Aldrich

Acétone

Acetone

suitable for HPLC, ≥99.8%

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About This Item

Formule linéaire :
CH3COCH3
Numéro CAS:
67-64-1
Poids moléculaire :
58.08
Beilstein:
635680
Numéro CE :
200-662-2
Numéro MDL:
MFCD00008765
Code UNSPSC :
12190000
eCl@ss :
39021201
ID de substance PubChem :
329755060
Nomenclature NACRES :
NA.02
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Qualité

HPLC grade

Densité de vapeur

2 (vs air)

Pression de vapeur

184 mmHg ( 20 °C)

Essai

≥99.8%

Forme

liquid

Température d'inflammation spontanée

465 °C (869 °F)

Limite d'explosivité

13.2 %

Technique(s)

HPLC: suitable

Impuretés

≤0.0005% non-volatile matter
≤0.002% free acid (as CH3COOH)
≤0.1% water (Karl Fischer)

Transmittance

330 nm, ≥15%
335 nm, ≥50%
340 nm, ≥80%
350 nm, ≥98%

Indice de réfraction

n20/D 1.359 (lit.)

pH

(5 - 6 at 395 g/l at 20 °C (68 °F))

pb

56 °C/760 mmHg (lit.)

Pf

−94 °C (lit.)

Solubilité

water: miscible

Densité

0.791 g/mL at 25 °C (lit.)

Application(s)

general analytical

Format

neat

Chaîne SMILES 

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

Clé InChI

CSCPPACGZOOCGX-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Mixtures of TiO2 (P25) with rare earth oxides (La2O3 or Y2O3) calcined at 700°C or 650°C efficiently causes oxidation of acetone.[1] Its Aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions.[2] It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide.[3] Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.[4]

Application

L′intensité de la luminescence de l′acétone dépend des constituants de la solution . L′absorption des rayonnements UV par l′acétone entraîne sa photolyse et la production de radicaux .
Acetone has been used in the preparation of 13wt% amorphous poly (lactic acid) (PLA) solution, which was required for the preparation of electrospun PLA membranes.[5]

Conditionnement

View returnable container options.

Autres remarques

Important notice
  • The article number 34850-4X2.5L-M will be discontinued. Please order the single bottle 34850-2.5L-M which is physically identical with the same exact specifications.
  • The article number 34850-6X1L-M will be discontinued. Please order the single bottle 34850-1L-M which is physically identical with the same exact specifications.

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Pictogrammes

FlameExclamation mark
GHS02,GHS07

Mention d'avertissement

Danger

Mentions de danger

H225,H319,H336

Classification des risques

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Organes cibles

Central nervous system

Risques supp

EUH066

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

1.4 °F - closed cup

Point d'éclair (°C)

-17.00 °C - closed cup

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
SDBB1655
SDBB1656
STBL4860
STBL4638
STBL4637

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a

Articles

Screening for Estrogen Active Nonylphenols in Water by Planar Solid Phase Extraction – Planar Yeast Estrogen Screen

Nonylphenols (NP) are ubiquitous substances that have been detected in highly diverse foodstuff. As breakdown products of nonylphenol ethoxylates, NP could end up in the aquatic environment. This article presents a rapid method for NP detection in surface water by planar solid phase extraction – planar yeast estrogen screen (pSPE-pYES).

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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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Reviews

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    • Review 1
    • Votes 0
    5 out of 5 stars.

    High quality solvent

    High quality product which performs well in my system

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  2. 1 Ratings-Only Review

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