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02578

Supelco

(±)-Épichlorhydrine

analytical standard

Synonyme(s) :

(±)-2-(Chlorométhyl)oxirane, 1-Chloro-2,3-époxypropane

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About This Item

Formule empirique (notation de Hill) :
C3H5ClO
Numéro CAS:
106-89-8
Poids moléculaire :
92.52
Beilstein:
79785
Numéro CE :
203-439-8
Numéro MDL:
MFCD00005132
Code UNSPSC :
41116107
ID de substance PubChem :
329747464
Nomenclature NACRES :
NA.24

73,50 $

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Qualité

analytical standard

Niveau de qualité

100

Densité de vapeur

3.2 (vs air)

Pression de vapeur

13.8 mmHg ( 21.1 °C)

Essai

≥99.9% (GC)

Température d'inflammation spontanée

779 °F

Durée de conservation

limited shelf life, expiry date on the label

Limite d'explosivité

21 %

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Indice de réfraction

n20/D 1.438 (lit.)
n20/D 1.438

pb

115-117 °C (lit.)

Pf

−57 °C (lit.)

Densité

1.183 g/mL at 25 °C (lit.)

Application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

Format

neat

Chaîne SMILES 

ClCC1CO1

InChI

1S/C3H5ClO/c4-1-3-2-5-3/h3H,1-2H2

Clé InChI

BRLQWZUYTZBJKN-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Epichlorohydrin (ECH) is a colorless, volatile and highly reactive organic compound which is utilized as a precursor in the production of glycerol, plastics, drugs and paints.[1][2]
This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food. Find all available reference materials for compounds listed in 10/2011 here

Application

ECH has been used as a reference standard for the identification of ECH in epoxy-coated cans by oxolane derivatization and gas chromatography−mass spectrometry (GC-MS) in selected ion monitoring (SIM) mode[2] and in drinking water by static headspace (HS) and purge and trap (P&T) coupled to GC equipped with an electron capture detector (GC-ECD).[3]
It may be used as a reference standard for the analysis of (±)-ECH in drinking water by ion chromatography[4] and in effluent water from wastewater treatment plants by HS-solid phase microextraction (HS-SPME) combined with GC-flame ionization detector (GC-FID) and GC-ECD.[1]

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B - Skin Sens. 1

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

82.4 °F

Point d'éclair (°C)

28 °C

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
BCCM9422
BCCJ6472
BCCF8256
BCCD0969
BCBZ7920

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Determination of epichlorohydrin by ion chromatography.
Sarzanini, et al.
Journal of Chromatography A, 884(1-2), 251-259 (2000)
New method for determination of epichlorohydrin in epoxy-coated cans by oxolane derivatization and gas chromatography-mass spectrometry.
Sung, et al.
Journal of Chromatography A, 1201(1), 100-105 (2008)
A convenient method for epichlorohydrin determination in water using headspace-solid-phase microextraction and gas chromatography.
Lasa, et al.
Journal of Chromatographic Science, 44(7), 438-443 (2006)
Static headspace and purge-and-trap gas chromatography for epichlorohydrin determination in drinking water.
Lucentini, et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 80(1), 89-98 (2005)
L Cody Smith et al.
Comparative biochemistry and physiology. Part D, Genomics & proteomics, 19, 159-173 (2016-05-09)
The diverse biological effects of xenoestrogens may be explained by their ability to differentially recruit co-regulatory proteins to the estrogen receptor (ER). We employed high-throughput receptor affinity binding and co-regulatory protein recruitment screening assays based on fluorescence polarization and time
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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