ALD00456

Sodium N-benzyloxycarbonyl-4-piperidinesulfinate

• Formule empirique (notation de Hill) : C₁₃H₁₆NNaO₄S
• Poids moléculaire : 305.33
• Code UNSPSC : 12352005
• ID de substance PubChem : 329772685
• Nomenclature NACRES : NA.22

Propriétés

• Forme: powder
• Capacité de réaction: reaction type: C-C Bond Formation; reaction type: C-H Activation
• Pertinence de la réaction: reagent type: catalyst
• Chaîne SMILES: O=S(O[Na])C1CCN(C(OCC2=CC=CC=C2)=O)CC1
• InChI: 1S/C13H17NO4S.Na/c15-13(18-10-11-4-2-1-3-5-11)14-8-6-12(7-9-14)19(16)17;/h1-5,12H,6-10H2,(H,16,17);/q;+1/p-1
• Clé InChI: LCXWFQBBQAGBHZ-UHFFFAOYSA-M

Description

Description générale

Sodium N-benzyloxycarbonyl-4-piperidinesulfinate is a sulfinate reagent bearing an N-substituted piperidine moiety.

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Autres remarques

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable