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901588

Sigma-Aldrich

1,3-Propanesultone solution

1 M in THF

Synonyme(s) :

1,2-Oxathiolane 2,2-dioxide, 3-Hydroxypropanesulfonic acid γ-sultone

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About This Item

Formule linéaire :
C3H6O3S
Numéro CAS:
1120-71-4
Numéro MDL:
MFCD00005355
Code UNSPSC :
12352200
Nomenclature NACRES :
NA.22

Forme

liquid

Concentration

1 M in THF

Indice de réfraction

n/D 1.4144

Densité

0.9266 g/mL

InChI

1S/C3H6O3S/c4-7(5)3-1-2-6-7/h1-3H2

Clé InChI

FSSPGSAQUIYDCN-UHFFFAOYSA-N

Application

1,3-Propanesultone has been used in:
  • preparation of poly[2-ethynyl-N-(propylsulfonate)pyridinium betaine], a new ionic conjugated polymer
  • preparation of novel poly(4-vinylpyridine) supported acidic ionic liquid catalyst
  • preparation of poly((2-(dimethylamino)ethyl methacrylate)-co-3-dimethyl(methacryloyloxyethyl)ammonium propanesulfonate)-coated mesoporous silica nanoparticles
  • sulfonation of surface of self-assembled nanoporous silica colloidal crystalline films comprised of 184nm-diameter silica spheres
Valuable building block or solvent offered as a solution in tetrahydrofuran for more convenient handling.

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Central nervous system, Respiratory system

Risques supp

EUH019

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

-2.0 °F

Point d'éclair (°C)

-18.88 °C

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Junke Wang et al.
Ultrasonics sonochemistry, 21(1), 29-34 (2013-06-12)
A novel poly(4-vinylpyridine) supported acidic ionic liquid catalyst was synthesized by the reaction of 4-vinylpyridine with 1,3-propanesultone, followed by the polymerization and the addition of the heteropolyacid. Due to the combination of polymer features and ionic liquid, it acted as
Stephen D Dertinger et al.
Environmental and molecular mutagenesis, 52(9), 748-755 (2011-11-05)
An international collaborative trial was established to systematically investigate the merits and limitations of a rat in vivo Pig-a gene mutation assay. The product of this gene is essential for anchoring CD59 to the plasma membrane, and mutations in this
Hermann M Bolt et al.
Toxicology letters, 151(1), 251-254 (2004-06-05)
1,3-Propane sultone is directly alkylating, genotoxic and carcinogenic. In rats, it induces local and systemic tumours at multiple target sites. Preponderant systemic tumours occur at the central nervous system, especially gliomas. Other localisations include the mammary gland, the intestine, the
D K Torous et al.
Mutation research, 465(1-2), 91-99 (2000-03-10)
Micronuclei (MN) are routinely enumerated in mouse peripheral blood to index genotoxicity. Recent data from the Collaborative Study Group for the Micronucleus Test (CSGMT) [CSGMT (The Collaborative Study Group for the Micronucleus Test), Evaluation of the rat micronucleus test with
Jiao-Tong Sun et al.
Macromolecular rapid communications, 33(9), 811-818 (2012-04-11)
A novel nanocontainer, which could regulate the release of payloads, has been successfully fabricated by attaching zwitterionic sulfobetaine copolymer onto the mesoporous silica nanoparticles (MSNs). RAFT polymerization is employed to prepare the hybrid poly(2-(dimethylamino)ethyl methacrylate)-coated MSNs (MSN-PDMAEMA). Subsequently, the tertiary
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