704091
Tributyltin hydride solution
1 M in cyclohexane
Synonyme(s) :
Tributylstannane, Tributylstannyl hydride
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About This Item
Formule empirique (notation de Hill):
C12H28Sn
Numéro CAS:
Poids moléculaire :
291.06
Numéro MDL:
Code UNSPSC :
12352103
ID de substance PubChem :
Nomenclature NACRES :
NA.22
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Forme
liquid
Pertinence de la réaction
reagent type: reductant
Concentration
1 M in cyclohexane
Indice de réfraction
n20/D 1.438
Densité
0.895 g/mL at 25 °C
Chaîne SMILES
CCCC[SnH](CCCC)CCCC
InChI
1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;
Clé InChI
DBGVGMSCBYYSLD-UHFFFAOYSA-N
Application
Reactant or reagent for:
- Alkyne hydrostannations
- Intramolcular cyclization for the synthesis of zoanthamine alkaloids
- Stereoselective C-glycosylation of pyranosides using Heck allylation
- Synthesis of phenylbutenoid dimers for use in treating diseases
- Preparation of N-acyl derivatives of ecteinascidin 770
- Syntehsis of cyclonucleosides using black light induced radical cyclization
Point d'éclair (°F)
5.0 °F
Point d'éclair (°C)
-15 °C
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Cassander P Titley-O'Neal et al.
The Science of the total environment, 449, 52-62 (2013-02-16)
Queen conch (Strombus gigas) are listed in CITES Appendix II. Populations may be declining due to anthropogenic inputs that include pollutants from boating activity. In the British Virgin Islands (BVI), some conch exhibit imposex, a condition in which male external
Robert W Chapman et al.
Molecular ecology, 22(6), 1485-1487 (2013-04-20)
Reproduction is the goal of living organisms, and environmental conditions that influence sexual development are therefore critical to understanding adaptation in natural populations. It is not surprising that so much attention has been devoted to the impacts of the physical
Shanshan Zhu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922, 21-26 (2013-02-19)
Analysis of tributyltin chloride (TBT) in environmental samples, such as seawater, is important in order to evaluate the TBT contamination and accumulation in the trophic chain. The environmental impact of organotin compounds has been a particular focus of analytical studies.
Detection, monitoring, and control of tributyltin--an almost complete success story.
Peter Matthiessen
Environmental toxicology and chemistry, 32(3), 487-489 (2013-02-19)
Raquel Chamorro-García et al.
Environmental health perspectives, 121(3), 359-366 (2013-01-17)
We have previously shown that exposure to tributyltin (TBT) modulates critical steps of adipogenesis through RXR/PPARγ and that prenatal TBT exposure predisposes multipotent mesenchymal stem cells (MSCs) to become adipocytes by epigenetic imprinting into the memory of the MSC compartment.
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