514586
4-Methoxy-TEMPO
97%
Synonyme(s) :
4-Methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy, free radical
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About This Item
Formule empirique (notation de Hill):
C10H20NO2
Numéro CAS:
Poids moléculaire :
186.27
Numéro MDL:
Code UNSPSC :
12352000
ID de substance PubChem :
Nomenclature NACRES :
NA.22
Produits recommandés
Essai
97%
Pf
40.5-44 °C (lit.)
Température de stockage
2-8°C
Chaîne SMILES
COC1CC(C)(C)N([O])C(C)(C)C1
InChI
1S/C10H20NO2/c1-9(2)6-8(13-5)7-10(3,4)11(9)12/h8H,6-7H2,1-5H3
Clé InChI
SFXHWRCRQNGVLJ-UHFFFAOYSA-N
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Description générale
4-Methoxy-TEMPO (4-methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy) is an aminoxyl free radical commonly employed for the oxidation reaction of alcohols (primary/secondary).[1] It has been proposed as hindered amine light stabiliser (HALS) model compound. Its reaction with irradiated dilute aqueous suspensions of photocatalytic nanoparticulate titanium dioxide was investigated by electron spin resonance (ESR) and electrospray ionization mass-spectrometry (ESI-MS).[2]
Application
4-Methoxy-TEMPO may be employed as catalyst for the synthesis of 2-substituted benzoxazoles, via aerobic oxidation reaction.[1]
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Équipement de protection individuelle
dust mask type N95 (US), Eyeshields, Gloves
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The kinetics of reduction of nitroxides including 4-hydroxy-TEMPO, 4-methoxy-TEMPO and 4-hexanoyloxy-TEMPO, which are of different lipophilicities, by vitamin C in cationic, non-ionic and anionic micelles, i.e. CTAB, Triton X-100 and SDS, respectively, have been studied by FSR spectroscopy by a
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Our work outlines the use of oxoammonium salts in a formal 1,2 addition process to olefins giving nucleoside analogs as products. Specifically, oxoammonium salts can be added to a solution of olefin and silylated heterocycle to give Methoxy TEMPO substituted
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