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245917

Sigma-Aldrich

Pentafluoropropionic acid

97%

Synonyme(s) :

Perfluoropropionic acid

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Disponible pour expédition le23 avril 2025Détails

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About This Item

Formule linéaire :
CF3CF2COOH
Numéro CAS:
422-64-0
Poids moléculaire :
164.03
Beilstein:
1773387
Numéro CE :
207-021-6
Numéro MDL:
MFCD00004170
Code UNSPSC :
12352100
ID de substance PubChem :
24854768
Nomenclature NACRES :
NA.22

84,40 $

Disponible pour expédition le23 avril 2025Détails

Devis pour commande en gros

Densité de vapeur

~5.6 (vs air)

Niveau de qualité

100

Pression de vapeur

~40 mmHg ( 20 °C)

Essai

97%

Forme

liquid

Indice de réfraction

n20/D 1.284 (lit.)

pb

96-97 °C (lit.)

Densité

1.561 g/mL at 25 °C (lit.)

Application(s)

PFAS testing

Groupe fonctionnel

carboxylic acid
fluoro

Chaîne SMILES 

OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C3HF5O2/c4-2(5,1(9)10)3(6,7)8/h(H,9,10)

Clé InChI

LRMSQVBRUNSOJL-UHFFFAOYSA-N

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Catégories apparentées

Description générale

The kinetics of the reaction of pentafluoropropionic acid with fluorine atoms was studied[1].

Application

Pentafluoropropionic acid (Perfluoropropionic acid) was used in the analysis of gentamicin with Gemini column by liquid chromatographic (LC) methods[2].
Pentafluoropropionic acid can be used to prepare 2-pentafluoropropylquinazolin-4(3H)-ones[3], perfluoroalkyl thioethers[4] and perfluoroalkyl-containing 3-azabicyclo[3.1.0]hexanes.[5]

Pictogrammes

Skull and crossbonesCorrosion
GHS06,GHS05

Mention d'avertissement

Danger

Mentions de danger

H290,H314,H331

Classification des risques

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
BCCM7310
MKCW9397
MKCV8846
MKCT6446
BCCJ8201

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Synthesis of perfluoroalkyl thioethers from aromatic thiocyanates by iron-catalysed decarboxylative perfluoroalkylation
Exner, Benjamin and Bayarmagnai, Bilguun and Matheis, Christian and Goossen, Lukas J
Journal of Fluorine Chemistry, 198, 89-93 (2017)
Enantioselective C-H Functionalization-Addition Sequence Delivers Densely Substituted 3-Azabicyclo [3.1. 0] hexanes
Pedroni, Julia and Cramer, Nicolai
Journal of the American Chemical Society, 139(36), 12398-12401 (2017)
One-Pot Synthesis of Trifluoromethylated Quinazolin-4 (3 H)-ones with Trifluoroacetic Acid as CF3 Source
Almeida, Sofia and Marti, Roger and Vanoli, Ennio and Abele, Stefan and Tortoioli, Simone
The Journal of Organic Chemistry, 83(9), 5104-5113 (2018)
E S Vasiliev et al.
The journal of physical chemistry. A, 118(23), 4013-4018 (2014-05-14)
The kinetics of the reaction between fluorine atoms and pentafluoropropionic acid has been studied experimentally at T = 262-343 K. The overall reaction rate constant decreases with temperature: k1(T) = 6.1 × 10(-13) exp(+1166 K)/T) cm(3) molecule(-1) s(-1). The potential
M H Choi et al.
Journal of chromatography. A, 897(1-2), 295-305 (2000-12-29)
An efficient method is described for the simultaneous determination of hair polyamines, such as 1,3-diaminopropane, putrescine, cadaverine, spermidine and spermine, by gas chromatography-mass spectrometry (GC-MS) with the selected ion-monitoring (SIM) mode. The method is based on the extractive two-phase ethoxycarbonyl
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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