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Principaux documents

209309

Sigma-Aldrich

Iron

powder, −325 mesh, 97%

Synonyme(s) :

Fe

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About This Item

Formule linéaire :
Fe
Numéro CAS:
Poids moléculaire :
55.85
Numéro CE :
Numéro MDL:
Code UNSPSC :
11101713
ID de substance PubChem :
Nomenclature NACRES :
NA.22
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Niveau de qualité

Essai

97%

Forme

powder

Pertinence de la réaction

core: iron
reagent type: catalyst

Résistivité

9.71 μΩ-cm

Taille des particules

−325 mesh

pb

2750 °C (lit.)

Pf

1535 °C (lit.)

Densité

7.86 g/mL at 25 °C (lit.)

Chaîne SMILES 

[Fe]

InChI

1S/Fe

Clé InChI

XEEYBQQBJWHFJM-UHFFFAOYSA-N

Application

Iron is generally used as a catalyst for wide variety of organic transformations. It has been used for the synthesis of magnetic polydimethylsiloxane (PDMS) for automated microcontact printing of biomolecules.[1]
Iron can also be used:
  • For the removal of arsenate from water.[2]
  • To synthesize Fe(III) iodide catalyst for thioglycosylation of peracetylated saccharides.[3]
  • As a catalyst for the graphitization for microscale radiocarbon analysis of small samples.[4]
  • For the removal of nitroaromatic pesticides by reduction.[5]

Forme physique

Hydrogen reduced

Pictogrammes

Flame

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Flam. Sol. 2 - Self-heat. 2

Code de la classe de stockage

4.2 - Pyrophoric and self-heating hazardous materials

Classe de danger pour l'eau (WGK)

nwg

Point d'éclair (°F)

69.8 °F

Point d'éclair (°C)

21 °C


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Certificats d'analyse (COA)

Lot/Batch Number

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Arsenate removal by zero valent iron: batch and column tests.
Biterna M, et al.
Journal of Hazardous Materials, 149(3), 548-552 (2007)
Fabrication of biomolecule microarrays for cell immobilization using automated microcontact printing.
Cell-Based Microarrays, 83-95 (2018)
Diastereoselective thioglycosylation of peracetylated glycosides catalyzed by in situ generated iron (III) iodide from elemental iodine and iron.
Weng SS
Tetrahedron Letters, 50(46), 6414-6417 (2009)
Technical progress in AMS microscale radiocarbon analysis.
Uchida M, et al.
Nucl. Instrum. Methods Phys. Res. Sect. B, 223(46), 313-317 (2004)
Reduction of nitroaromatic pesticides with zero-valent iron.
Keum Y S and Li Q X
Chemosphere, 54(3), 255-263 (2004)

Articles

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Are the particles spherical or some other morphology?

    1 answer
    1. The material is supplied with a crushed irregular shape. Any other morphology information is not determined.

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