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8.18823

Sigma-Aldrich

Sodium borohydride

(tablets) for synthesis

Synonym(s):

Sodium borohydride, Sodium tetrahydridoborate

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25 G
$75.00
100 G
$191.00

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25 G
$75.00
100 G
$191.00

About This Item

Empirical Formula (Hill Notation):
H4BNa
CAS Number:
Molecular Weight:
37.83
MDL number:
UNSPSC Code:
12352306
EC Index Number:
241-004-4
NACRES:
NA.22
form:
solid

$75.00


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vapor pressure

<1 hPa ( 25 °C)

Quality Level

form

solid

autoignition temp.

220 °C

potency

160 mg/kg LD50, oral (Rat)
230 mg/kg LD50, skin (Rabbit)

expl. lim.

3.02 % (v/v)

reaction suitability

reagent type: reductant

pH

11 (20 °C, 10 g/L in H2O)

bp

500 °C (decomposition)

mp

>360 °C (slow decomposition)

transition temp

flash point 69 °C

density

1.07 g/cm3 at 20 °C

bulk density

350‑500 kg/m3

storage temp.

2-30°C

SMILES string

[Na][BH4]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

General description

Sodium borohydride (NaBH4) is the most commonly available borohydride used in several industrial applications. It is considered a selective reducing agent due to its ability to selectively reduce aldehydes and ketones into their corresponding alcohols in the presence of other functional groups such as nitro, ester, amide, lactone, epoxide, and nitriles. Ethanol and methanol are usually employed as solvents in NaBH4 reduction reactions.[1]

Application

Sodium borohydride (tablets form) can be used as a potential candidate to store as well as generate hydrogen for energy-carrier,applications.[2]

Analysis Note

Assay (hypochlorite): ≥ 96.0 %
Identity (ICP-OES): passes test

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Customers Also Viewed

Sodium Borohydride
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eEROS (Encyclopedia of Reagents for Organic Synthesis) (2014)
Hydrogen generation by both acidic and catalytic hydrolysis of sodium borohydride
Netskina OV, et al.
Catalysis for Sustainable Energy, 5(1), 41-48 (2018)

Questions

  1. Hi, there is no information on the properties of the tablets provided. How much does each tablet weigh? Are they 100% NaBH4, or do they contain any excipients? Are they provided in individual blister packs or in bulk?

    1 answer
    1. This product is a 6.35 mm diameter x 12.7 mm length caplet. The weight range per caplet is 0.98 - 1.02 g each. The minimum purity is 96% NaBH4. The identify of the impurities is not determined. Any excipient or binder components are considered proprietary. The caplets are package in glass bottles. Please note that this product is M-Clarity level MQ200 and is for R&D use only. Details regarding this grading system may be accessed at the link below:
      https://www.sigmaaldrich.com/US/en/life-science/quality-and-regulatory-management/m-clarity-program

      Helpful?

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