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926094

Sigma-Aldrich

(R)-RUCY™-XylBINAP

Takasago

Synonym(s):

RuCl[(R)-daipena][(R)-xylbinap]

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250 MG
$103.00
1 G
$302.00
5 G
$827.00

$103.00

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250 MG
$103.00
1 G
$302.00
5 G
$827.00

About This Item

Empirical Formula (Hill Notation):
C71H73ClN2O2P2Ru
CAS Number:
1384974-38-2
Molecular Weight:
1184.82
MDL number:
MFCD20261161
UNSPSC Code:
12352116
NACRES:
NA.22

$103.00

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Quality Level

100

form

powder

reaction suitability

reagent type: ligand

functional group

phosphine

SMILES string

[Ru+]c9c(ccc(c9)OC)C(N)([C@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]

InChI

1S/C52H48P2.C19H25N2O2.ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-

InChI key

VBDGCLWXZBVBHR-LOJLRZLHSA-M

Application

(R)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.

Other Notes

Chiral Ruthenabicyclic Complexes: Precatalysts for Rapid, Enantioselective, and Wide-Scope Hydrogenation of Ketones

Legal Information

Product of Takasago.

For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.

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Description
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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and

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