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Sigma-Aldrich

Benzyl benzodithioate

96%

Synonym(s):

BDTB, Benzenecarbodithioic acid, phenylmethyl ester, Benzyl benzenecarbodithioate, Benzyl dithiobenzoate, Benzyl phenyl RAFT agent

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About This Item

Empirical Formula (Hill Notation):
C14H12S2
CAS Number:
27249-90-7
Molecular Weight:
244.38
MDL number:
MFCD08705657
UNSPSC Code:
12352100
PubChem Substance ID:
329766863
NACRES:
NA.23

Assay

96%

form

powder

refractive index

n20/D 1.696

density

1.182 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

S=C(SCc1ccccc1)c2ccccc2

InChI

1S/C14H12S2/c15-14(13-9-5-2-6-10-13)16-11-12-7-3-1-4-8-12/h1-10H,11H2

InChI key

ZCKPFAYILJKXAT-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; Chain Transfer Agent (CTA) well-suited for methacrylates, methacrylamides, and styrenes.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H317,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

No data available

Flash Point(C)

No data available

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Liping Zhao et al.
Analytical and bioanalytical chemistry (2018-06-18)
Fabrication of polymer membranes with nanopores and a confinement effect toward enzyme immobilization has been an enabling endeavor. In the work reported here, an enzyme reactor based on a thermoresponsive magnetic porous block copolymer membrane was designed and constructed. Reversible
Yiyi Liu et al.
ACS nano, 13(6), 6760-6769 (2019-05-31)
Thiol-polystyrene (SH-PS)-capped plasmonic nanoparticles can be fabricated into free-standing, one-nanoparticle-thick superlattice sheets (termed plasmene) based on physical entanglement between ligands, which, however, suffer from irreversible dissociation in organic solvents. To address this issue, we introduce coumarin-based photo-cross-linkable moieties to the
Liping Zhao et al.
Journal of chromatography. A, 1548, 104-110 (2018-03-28)
A chiral ligand exchange capillary electrochromatography (CLE-CEC) protocol was designed and implemented for d,l-amino acids enantioseparation with poly(maleic anhydride-styrene-methacryloyl-l-arginine methyl ester) as the coating. The block copolymer was synthesized through the reversible addition fragmentation chain transfer reaction. In the constructed
Ali Azizi et al.
Journal of chromatography. A, 1610, 460534-460534 (2019-09-22)
Magnetic molecularly imprinted polymers (MMIPs) combine nanotechnology and molecular imprinting technology to offer selective and tunable enrichment for water analysis. In this paper, a selective sorbent was prepared by surface polymerization onto magnetic Fe3O4@SiO2 nanoparticles through reversible addition fragmentation chain
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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