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742457

Sigma-Aldrich

1-(Azidomethyl)-4-bromobenzene solution

~0.5 M in dichloromethane, ≥96.0% (HPLC)

Synonym(s):

p-Bromobenzyl azide solution

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About This Item

Empirical Formula (Hill Notation):
C7H6BrN3
CAS Number:
107047-10-9
Molecular Weight:
212.05
Beilstein:
4904917
MDL number:
MFCD11637147
UNSPSC Code:
12352200
PubChem Substance ID:
329765575

Assay

≥96.0% (HPLC)

form

solution

reaction suitability

reaction type: click chemistry

concentration

~0.5 M in dichloromethane

impurities

≤2.0% water

storage temp.

2-8°C

SMILES string

Brc1ccc(CN=[N+]=[N-])cc1

InChI

1S/C7H6BrN3/c8-7-3-1-6(2-4-7)5-10-11-9/h1-4H,5H2

InChI key

MOKKTDQWMSOCAF-UHFFFAOYSA-N

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Statements

H315,H319,H336,H351,H372

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Dermal - STOT SE 3

Target Organs

Central nervous system, Lungs,Nervous system,Cardio-vascular system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCBG1679V
BCBG1679

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Matthew D Graaf et al.
ACS chemical biology, 11(10), 2829-2837 (2016-10-22)
Cu(I)-catalyzed "click" reactions cannot be performed on a borate ester derived polymer coating on a microelectrode array because the Cu(II) precursor for the catalyst triggers background reactions between both acetylene and azide groups with the polymer surface. Fortunately, the Cu(II)-background

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