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528595

Sigma-Aldrich

2,6-Diethoxybenzoic acid

97%

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About This Item

Linear Formula:
(C2H5O)2C6H3CO2H
CAS Number:
82935-36-2
Molecular Weight:
210.23
MDL number:
MFCD00156982
UNSPSC Code:
12352100
PubChem Substance ID:
24877599
NACRES:
NA.22

Assay

97%

form

solid

mp

131-135 °C (lit.)

SMILES string

CCOc1cccc(OCC)c1C(O)=O

InChI

1S/C11H14O4/c1-3-14-8-6-5-7-9(15-4-2)10(8)11(12)13/h5-7H,3-4H2,1-2H3,(H,12,13)

InChI key

XUIVSLVJEQVKLB-UHFFFAOYSA-N

General description

2,6-Diethoxybenzoic acid undergoes catalytic hydrodecarboxylation in the presence of toluene/D2O to afford 2-d-1,3-diethoxybenzene.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Jing Zhang et al.
Journal of the American Chemical Society, 135(46), 17270-17273 (2013-11-01)
Through-space metal/hydrogen shift is an important strategy for transition-metal-catalyzed C-H bond activation. Here we describe the synthesis and characterization of a Rh(I) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a highly unusual 1,3-rhodium migration. This aryl-to-aryl 1,3-Rh/H shift was also

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