449903

Lithium fluoride

≥99.99% trace metals basis

• Synonym(s): Fluorolithium
• Linear Formula: LiF
• CAS Number: 7789-24-4
• Molecular Weight: 25.94
• EC Number: 232-152-0
• MDL number: MFCD00011090
• UNSPSC Code: 12352302
• PubChem Substance ID: 24868518
• NACRES: NA.23

Properties

• grade: anhydrous
• Assay: ≥99.99% trace metals basis
• form: powder and chunks
• greener alternative product characteristics: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• impurities: ≤100.0 ppm Trace Metal Analysis
• bp: 1673 °C/1 atm (lit.)
• mp: 845 °C (lit.)
• solubility: aqueous acid: slightly soluble(lit.)
• density: 2.64 g/mL at 25 °C (lit.)
• greener alternative category: Enabling
• SMILES string: [Li+].[F-]
• InChI: 1S/FH.Li/h1H;/q;+1/p-1
• InChI key: PQXKHYXIUOZZFA-UHFFFAOYSA-M

Description

General description

Lithium fluoride is a white crystalline solid with a high melting point. It is widely applied in the field of rechargeable batteries, storage devices, and thermoluminescent materials. LiF is also used as a coupling layer in OLED or PLED devices to enhance electron injection. On the other hand, it is preferred for optical applications due to its wide band gap, which allows it to transmit light efficiently.

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Application

Lithium fluoride can be used:

• As an additive to fabricate SiO@C/graphite composite anode materials for Li-ion batteries. LiF stabilizes solid electrolyte interphase (SEI) and enhances initial coulombic efficiency.
• As a critical component in SEI for stabilizing the SEI layer and improving the cycling efficiency of Li metal batteries.
• To fabricate electron contacts for high-efficiency n-type crystalline silicon solar cells.
• To prepare solid-state light sources for radiation imaging detectors.
• To synthesize highly crystalline MXene for asymmetric supercapacitor applications. And also, lightweight, flexible, and hydrophobic MXene foam with reasonable strength, high electrical conductivity, and an outstanding EMI-shielding performance.
• As an electron-injection layer to fabricate ITO/PEDOT:PSS/perovskite/B₃PYMPM/ LiF/Al OLED device with a quantum efficiency of 20%.

Safety Information

• Pictograms: GHS06
• Signal Word: Danger
• Hazard Statements: H301,H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH032
• Storage Class Code: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves