447145

Borane dimethyl sulfide complex solution

5.0 M in diethyl ether

• Synonym(s): BMS, Trihydro[thiobis[methane]]boron
• Linear Formula: (CH₃)₂S · BH₃
• CAS Number: 13292-87-0
• Molecular Weight: 75.97
• Beilstein: 3663489
• MDL number: MFCD00013189
• UNSPSC Code: 12352112
• PubChem Substance ID: 24868320
• NACRES: NA.22

Properties

• reaction suitability: reagent type: reductant
• concentration: 5.0 M in diethyl ether
• bp: ~34 °C
• density: 0.789 g/mL at 25 °C
• functional group: thioether
• storage temp.: 2-8°C
• SMILES string: B.CSC
• InChI: 1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
• InChI key: RMHDLBZYPISZOI-UHFFFAOYSA-N

Description

Application

Borane dimethyl sulfide complex can be used in the preparation of:

• An amine-based polymer for CO₂ uptake.
• Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
• Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

Reactant used as a regioselective reducing agent

Reactant involved in:

• Hydroboration / oxidation

Synthesis of cage compounds

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS05
• Signal Word: Danger
• Hazard Statements: H224,H260,H301 + H311,H318,H336,H360FD,H412
• Precautionary Statements: P210 - P231 + P232 - P233 - P280 - P301 + P310 - P305 + P351 + P338 - P403 + P233
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1
• Target Organs: Central nervous system
• Supplementary Hazards: EUH014,EUH019,EUH066
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 1
• Flash Point(F): -31.0 °F - closed cup
• Flash Point(C): -35 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves