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About This Item
Empirical Formula (Hill Notation):
C2H4N4S
CAS Number:
Molecular Weight:
116.14
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
form
powder
mp
125-128 °C (lit.)
SMILES string
Cn1nnnc1S
InChI
1S/C2H4N4S/c1-6-2(7)3-4-5-6/h1H3,(H,3,5,7)
InChI key
XOHZHMUQBFJTNH-UHFFFAOYSA-N
General description
5-Mercapto-1-methyltetrazole is a heterocyclic thiol derivative. It forms dimeric or tetrameric complexes with trimethylgallium.[1]
Application
5-Mercapto-1-methyltetrazole may be employed as heterocyclic ligand to study the geometry and stereochemical activity of the lone pair at the lead atom in hemi- and holo-directed lead(II) complexes.[2] It may be used in the chemical modification of submicron particles of mesoporous MSU-2 silica[3] and SBA-15 mesoporous silica.[4]
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
4.1A - Other explosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Damián Pérez-Quintanilla et al.
Journal of hazardous materials, 166(2-3), 1449-1458 (2009-01-23)
A SBA-15 mesoporous silica has been chemically modified with 5-mercapto-1-methyltetrazole. The newly synthesized material (MTTZ-SBA-15) has been characterized, by powder X-ray diffraction, N(2) adsorption, FT-IR, (13)C NMR spectroscopy and elemental analysis, and used to preconcentrate Zn(II) in water samples. The
P A Bombardt et al.
Journal of pharmaceutical and biomedical analysis, 8(1), 73-77 (1990-01-01)
A simple, fast and sensitive method for the quantitative determination of 1-methyl-1H-tetrazole-5-thiol using HPLC is reported. Samples are deproteinated by plasma water filtration and injected into a HPLC system capable of column switching and backflushing the analytical column. The limit
W Peetermans et al.
Acta clinica Belgica, 45(5), 327-333 (1990-01-01)
Treatment with MTT side chain containing cephalosporins can result in a clinically relevant coagulopathy due to a deficiency in active vitamin K dependent clotting factors. This complication is not caused by a decreased production of vitamin K by the intestinal
L S Welage et al.
Antimicrobial agents and chemotherapy, 33(6), 857-861 (1989-06-01)
The N-methylthiotetrazole side chain (NMTT) that is present on several cephalosporins has been implicated in the development of antibiotic-associated hypoprothrombinemia. A randomized three-way crossover trial was conducted to compare the release of the NMTT side chain from three NMTT-containing antibiotics.
J S Tibbitts et al.
Drug metabolism and drug interactions, 7(2-3), 149-160 (1989-01-01)
The effect of biliary diversion on the ability of cefamandole, a methyltetrazole-thiol (MTT) containing antibiotic, to alter both hepatic vitamin K metabolism and the gamma-carboxylation of glutamic acid were examined in the rat, in order to understand the hypoprothrombinemia associated
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