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Assay
96%
form
solid
mp
146-148 °C (lit.)
functional group
bromo
ketone
SMILES string
Brc1ccc2-c3ccccc3C(=O)c2c1
InChI
1S/C13H7BrO/c14-8-5-6-10-9-3-1-2-4-11(9)13(15)12(10)7-8/h1-7H
InChI key
MTCARZDHUIEYMB-UHFFFAOYSA-N
Application
2-Bromo-9-fluorenone was used:
- as end-capping agent for poly(9,9-dialkylfluorene-2,7-diyl) derivatives
- in preparation of spirobifluorene ligands
- in synthesis of altitudinal molecular motors which contain functional groups in their rotor part
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Oxidative stability and its effect on the photoluminescence of poly (fluorene) derivatives: end group effects.
Chemistry of Materials, 11(4), 1083-1088 (1999)
Novel iridium complexes as high-efficiency yellow and red phosphorescent light emitters for organic light-emitting diodes.
Tetrahedron, 64(48), 10814-10820 (2008)
Chemistry (Weinheim an der Bergstrasse, Germany), 19(32), 10690-10697 (2013-06-21)
We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were
International journal of molecular sciences, 14(11), 22368-22379 (2013-11-16)
Supramolecular luminescence stems from non-covalent exciton behaviors of active π-segments in supramolecular entities or aggregates via intermolecular forces. Herein, a π-conjugated oligofluorenol, containing self-complementary double hydrogen bonds, was synthesized using Suzuki coupling as a supramolecular semiconductor. Terfluorenol-based random supramolecular polymers
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