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292753

Sigma-Aldrich

Pentaethylenehexamine

technical grade

Synonym(s):

3,6,9,12-Tetraazatetradecane-1,14-diamine

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250 ML
$67.20
1 L
$173.00

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250 ML
$67.20
1 L
$173.00

About This Item

Linear Formula:
NH2CH2CH2NH(CH2CH2NH)3CH2CH2NH2
CAS Number:
4067-16-7
Molecular Weight:
232.37
Beilstein:
1768042
EC Number:
223-775-9
MDL number:
MFCD00008167
UNSPSC Code:
12352100
PubChem Substance ID:
24857609
NACRES:
NA.22

$67.20

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grade

technical grade

refractive index

n20/D 1.5096 (lit.)

solubility

water: soluble 500 g/L at 20 °C

density

0.95 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

NCCNCCNCCNCCNCCN

InChI

1S/C10H28N6/c11-1-3-13-5-7-15-9-10-16-8-6-14-4-2-12/h13-16H,1-12H2

InChI key

LSHROXHEILXKHM-UHFFFAOYSA-N

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General description

Pentaethylenehexamine (PEHA) is an acyclic polyamine that can be used to prepare amine-modified adsorbent.[1][2]

Application

5.Pentaethylenehexamine has been used in the preparation of:
  • polyisobutylene succinimide (PIBSI) dispersants, used as engine oil-additives[3]
  • poly(glycidyl methacrylate) (P(GMA)) homopolymers[4]
  • poly(amidoamine)s[5]

Signal Word

Danger

Hazard Statements

H314,H317,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM0884
BCCK0480
BCCH1076
BCCD0231
BCBX5551

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Pentaethylenehexamine loaded SBA-16 for CO2 capture from simulated flue gas
Liu Y, et al.
Powder Technology, 318, 186-192 (2017)
Gunniya Hariyanandam Gunasekar et al.
Inorganic chemistry, 58(6), 3717-3723 (2019-03-02)
Today, one of the most imperative targets to realize the conversions of CO2 in industry is the development of practically viable catalytic systems that demonstrate excellent activity, selectivity, and durability. Herein, a simple heterogeneous Ru(III) catalyst is prepared by immobilizing
Gas-phase H/D exchange reactions of polyamine complexes:(M+ H)+,(M+ alkali metal+), and (M+ 2H) 2+
Reyzer ML and Brodbelt JS
Journal of the American Society For Mass Spectrometry, 11, 711-721 (2000)
Solmaz Pirouz et al.
The journal of physical chemistry. B, 118(14), 3899-3911 (2014-03-19)
A novel methodology based on fluorescence quenching measurements is introduced to determine quantitatively the amine content of polyisobutylene succinimide (PIBSI) dispersants used as engine oil-additives. To this end, a series of five PIBSI dispersants were prepared by reacting 2 mol
Lisa E Prevette et al.
Biomacromolecules, 11(2), 326-332 (2010-01-12)
Previously, a series of three poly(amidoamine)s was designed and synthesized by polymerizing oxylate, succinate, or adipate groups with pentaethylenehexamine. These resulting polymers (named O4, S4, and A4, respectively) were created as models to poly(glycoamidoamine) nucleic acid delivery agents to understand
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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