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148083

Sigma-Aldrich

1,1,1-Tris(hydroxymethyl)propane

97%

Synonym(s):

2-Ethyl-2-hydroxymethyl-1,3-propanediol, Trimethylolpropane

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About This Item

Linear Formula:
CH3CH2C(CH2OH)3
CAS Number:
77-99-6
Molecular Weight:
134.17
Beilstein:
1698309
EC Number:
201-074-9
MDL number:
MFCD00004694
UNSPSC Code:
12352100
PubChem Substance ID:
24848880
NACRES:
NA.22

vapor density

4.8 (vs air)

vapor pressure

<1 mmHg ( 20 °C)

Assay

97%

form

(Powder or Crystals or Granules or Chunks)

autoignition temp.

1301 °F

bp

159-161 °C/2 mmHg (lit.)

mp

56-58 °C (lit.)

SMILES string

CCC(CO)(CO)CO

InChI

1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3

InChI key

ZJCCRDAZUWHFQH-UHFFFAOYSA-N

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Application

1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.

Pictograms

Health hazard
GHS08

Signal Word

Warning

Hazard Statements

H361fd

Hazard Classifications

Repr. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

356.0 °F - Cleveland open cup

Flash Point(C)

180 °C - Cleveland open cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
Stephanie E A Gratton et al.
Journal of controlled release : official journal of the Controlled Release Society, 121(1-2), 10-18 (2007-07-24)
A novel method for the fabrication of polymeric particles on the order of tens of nanometers to several microns is described. This imprint lithographic technique called PRINT (Particle Replication In Non-wetting Templates), takes advantage of the unique properties of elastomeric
Daniel Cohn et al.
Biomaterials, 25(27), 5875-5884 (2004-06-03)
This article introduces novel biocompatible tissue adhesives that do not involve any chemical or biochemical reactions, during their application in vivo. The use of these new adhesives is based exclusively on their temperature-dependent rheological properties. Since biocompatibility and biodegradability are
Y Y Linko et al.
Journal of biotechnology, 66(1), 41-50 (1998-12-29)
The interest in the applications of biocatalysis in organic syntheses has rapidly increased. In this context, lipases have recently become one of the most studied groups of enzymes. We have demonstrated that lipases can be used as biocatalyst in the
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