Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
700479
Ferrocenylmethyl methacrylate
95% (NMR), contains Ionol® 46 (Raschig GmbH) as inhibitor
Synonym(s):
FMMA
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About This Item
Empirical Formula (Hill Notation):
C15H16FeO2
CAS Number:
Molecular Weight:
284.13
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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Assay
95% (NMR)
form
solid
contains
Ionol® 46 (Raschig GmbH) as inhibitor
mp
52-54 °C
storage temp.
−20°C
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.CC(=C)C(=O)OC[C]2[CH][CH][CH][CH]2
InChI
1S/C10H11O2.C5H5.Fe/c1-8(2)10(11)12-7-9-5-3-4-6-9;1-2-4-5-3-1;/h3-6H,1,7H2,2H3;1-5H;
InChI key
GSPYKNCYLXXOJO-UHFFFAOYSA-N
Legal Information
Ionol is a registered trademark of Raschig GmbH
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Hoik Lee et al.
Polymers, 12(11) (2020-11-04)
We demonstrate an electrospray/electrospinning process to fabricate stimuli-responsive nanofibers or particles that can be utilized as stimuli-responsive drug-loaded materials. A series of random copolymers consisting of hydrophobic ferrocene monomers and hydrophilic carboxyl groups, namely poly(ferrocenylmethyl methacrylate-r-methacrylic acid) [poly(FMMA-r-MA)] with varied
Yoonhee Na et al.
Journal of materials chemistry. B, 8(9), 1906-1913 (2020-02-12)
Ferrocene-containing nanoparticles show reversible redox activity that could trigger drug release mediated by reactive oxygen species (ROS). In this study, four ferrocene-containing polymers, comprising ferrocenylmethyl methacrylate (FMMA)-methacrylic acid (MA) random copolymers, i.e., poly(FMMA-r-MA), were synthesized via radical polymerization, resulting in
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What is the Department of Transportation shipping information for this product?
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What is the inhibitor used in Product No. 700479, Ferrocenylmethyl methacrylate?
1 answer-
The inhibitor used in this product is 2,2´-methylenebis(6-tert-butyl-4-methylphenol) (CAS registry number [119-47-1]), which is a non-discoloring and non-staining stabilizer. It is widely used in industry especially in natural and synthetic rubber.
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How does the storage temperature relate to shipping conditions?
1 answer-
The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.
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How can the monomer ferrocenylmethyl methacrylate, Product 700479, be polymerized?
1 answer-
Generally, Product No. 700479 can be polymerized with an anionic initiator such as butyllithium (Product No. 230707) or lithium aluminum hydride (Product No. 531502). Or it can be radically polymerized using an initiator such as 2,2´-Azobis(2-methylpropionitrile) (AIBN, Product No. 44109).
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What applications can Product 700479, Ferrocenylmethyl methacrylate, be used for?
1 answer-
Thin films of poly- ferrocenylmethyl methacrylate can be used for biosensing applications, taking advantage of the redox behavior of the ferrocenyl unit.
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