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About This Item
Linear Formula:
IC6H4COCl
CAS Number:
Molecular Weight:
266.46
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
solid
bp
120-121 °C/1 mmHg (lit.)
mp
63-65 °C (lit.)
functional group
acyl chloride
iodo
SMILES string
ClC(=O)c1ccc(I)cc1
InChI
1S/C7H4ClIO/c8-7(10)5-1-3-6(9)4-2-5/h1-4H
InChI key
NJAKCIUOTIPYED-UHFFFAOYSA-N
Application
4-Iodobenzoyl chloride has been used in:
- modification of poly(allylamine), to make the polymer x-ray visible[1]
- preparation of series of N-(1-benzylpyrrolidin-3-yl)arylbenzamides, potential human dopamine D4 antagonists[2]
- preparation of [2] rotaxane monomer, for poly [2] rotaxane synthesis[3]
- synthesis of pyrroles from imines and acetylenes mediated by isocyanides versus palladium catalysis[4]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Daniel J St Cyr et al.
Organic letters, 9(3), 449-452 (2007-01-26)
[reaction: see text] A direct synthesis of pyrroles from imines, acid chlorides, and alkynes mediated by isocyanides is reported. This reaction proceeds with a range of each of these three substrates, providing a method to generate families of pyrroles in
Ni Chen et al.
Journal of Asian natural products research, 22(5), 444-451 (2019-03-20)
A series of aromatic or long-chain chrysin derivatives (1-10) were synthesized by esterification of chrysin and acyl chloride. The chemical structures of these compounds were determined by mass spectrum (MS), 1H NMR, and 13C NMR spectra. Though aromatic chrysin derivatives
Damia Mawad et al.
Nanotechnology, 21(33), 335603-335603 (2010-07-27)
Contrast agents are currently used in a variety of diagnostic imaging techniques, including computer tomography for early cancer detection. Radiopaque nanoparticles have recently been proposed as an alternative method to traditional contrast agents that may allow for long-term image tracking.
Synthesis of poly [2] rotaxane by Sonogashira polycondensation.
Sasabe H, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 45(17), 4154-4160 (2007)
Ian Egle et al.
Bioorganic & medicinal chemistry letters, 14(19), 4847-4850 (2004-09-03)
A series of N-(1-benzylpyrrolidin-3-yl)arylbenzamides 8 has been prepared, and their structure-activity relationships studied. Potent ligands selective for human D(4) (hD(4)) over hD(2) and alpha(1) have been identified. One example was determined to be an antagonist in a cAMP assay, with
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