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157740

Sigma-Aldrich

Iron(III) chloride

greener alternative

reagent grade, 97%

Synonym(s):

Ferric chloride, Iron trichloride, Molysite

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About This Item

Linear Formula:
FeCl3
CAS Number:
Molecular Weight:
162.20
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

reagent grade

Quality Level

vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

Assay

97%

form

powder

greener alternative product characteristics

Catalysis
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mp

304 °C (lit.)

greener alternative category

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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General description

Iron(III) chloride is a mild oxidizing agent and participates in various carbon-carbon-bond forming reactions. On crystallization with water, it forms hydrates. It can be prepared by reacting chlorine with the scrap iron at approximately 650°C.
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Application

Iron(III) chloride (Ferric Chloride, FeCl3) has been used as a surface modulator for the characterization of wines by fingerprinting technology. It has been used for the quantitative estimation of sulfide in various biological samples.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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"Iron (III) chloride-catalyzed convenient one-pot synthesis of homoallyl benzyl ethers starting from aldehydes"
Watahiki T, et al.
Organic Letters, 5(17), 3045-3048 (2003)
Novel non-specific liquid fingerprint technology for wine analysis: a feasibility study.
Siivonen JJ, et al.
Australian Journal of Grape and Wine Research, 20(2), 172-177 (2014)
"Iron (III) chloride-based mild synthesis of phenanthrene and its application to total synthesis of phenanthroindolizidine alkaloids"
Wang L-K, et al.
Tetrahedron, 64(32), 7504-7510 (2008)
Yuanyuan Kong et al.
Cell death & disease, 10(9), 624-624 (2019-08-20)
Recent findings demonstrate that aberrant downregulation of the iron-exporter protein, ferroportin (FPN1), is associated with poor prognosis and osteoclast differentiation in multiple myeloma (MM). Here, we show that FPN1 was downregulated in MM and that clustered regularly interspaced short palindromic
Shaun Martin et al.
Parkinson's disease, 2016, 9531917-9531917 (2016-04-14)
The late endo-/lysosomal P-type ATPase ATP13A2 (PARK9) is implicated in Parkinson's disease (PD) and Kufor-Rakeb syndrome, early-onset atypical Parkinsonism. ATP13A2 interacts at the N-terminus with the signaling lipids phosphatidic acid (PA) and phosphatidylinositol (3,5) bisphosphate (PI(3,5)P2), which modulate ATP13A2 activity

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