409405

Chlorotris(trimethylsilyl)silane

97%

• Synonym(s): 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride
• Linear Formula: [(CH₃)₃Si]₃SiCl
• CAS Number: 5565-32-2
• Molecular Weight: 283.11
• MDL number: MFCD01321222
• UNSPSC Code: 12352101
• PubChem Substance ID: 24865643
• NACRES: NA.22

Properties

• Assay: 97%
• form: solid
• mp: 50-52 °C (lit.)
• SMILES string: C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
• InChI key: HCOROOJWVHFMRJ-UHFFFAOYSA-N

Description

General description

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.

Application

Super Silyl Protecting Groups

Used for:

• Insertion into a P-P bond
• Diastereoselective aldol and cascade reactions
• Preparation of hypersilyl substituted monophosphines and diphosphines

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Danger
• Hazard Statements: H228,H261,H315,H319,H335
• Precautionary Statements: P210 - P231 + P232 - P240 - P241 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH029
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 87.8 °F - closed cup
• Flash Point(C): 31 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves