32058
Pirimiphos-methyl
PESTANAL®, analytical standard
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About This Item
Empirical Formula (Hill Notation):
C11H20N3O3PS
CAS Number:
Molecular Weight:
305.33
Beilstein:
755726
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
Recommended Products
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
storage temp.
2-8°C
SMILES string
CCN(CC)c1nc(C)cc(OP(=S)(OC)OC)n1
InChI
1S/C11H20N3O3PS/c1-6-14(7-2)11-12-9(3)8-10(13-11)17-18(19,15-4)16-5/h8H,6-7H2,1-5H3
InChI key
QHOQHJPRIBSPCY-UHFFFAOYSA-N
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General description
Pirimiphos-methyl (PMM) is an organophosphorous pesticide.
Application
PMM may have been used as reference standard for identification of possible intermediate products formed during photocatalytic degradation of PMM using different chromatographic methods, like GC, HPLC, GC-MS, TOC and LC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 1 - STOT SE 1
Target Organs
Nervous system
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Photocatalytic degradation of pesticide pirimiphos-methyl: Determination of the reaction pathway and identification of intermediate products by various analytical methods.
Herrmann, Jean Marie, et al.
Catalysis Today, 54.2, 353-367 (1999)
Luigi Lucini et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 46(6), 518-524 (2011-07-06)
The aim of this work was to comparatively assess the persistence of pirimiphos methyl residues in cereals and in their milling fractions after spray application in post harvest. An analytical method, based on a slightly modified QuEChERS extraction followed by
Determining pirimiphos-methyl in durum wheat samples using an acetylcholinesterase inhibition assay.
Michele Del Carlo et al.
Analytical and bioanalytical chemistry, 381(7), 1367-1372 (2005-03-05)
An electrochemical assay used for detecting acetylcholinesterase (AChE) inhibitors has been optimised to detect pirimiphos-methyl in durum wheat. Pirimiphos-methyl is a phosphothionate insecticide and so it needs to be transformed into the corresponding oxo form to act as an effective
Young-Su Jang et al.
Journal of the American Mosquito Control Association, 21(4), 400-403 (2006-03-02)
Mosqutio larvicidal activity of Chamaecyparis obtusa leaf-derived materials against the 4th-stage larvae of Aedes aegypti (L.), Ochlerotatus togoi (Theobald), and Culex pipiens pallens (Coquillett) was examined in the laboratory. A crude methanol extract of C. obtusa leaves was found to
M O Lawal et al.
Pakistan journal of biological sciences : PJBS, 13(8), 405-408 (2010-09-15)
Pirimiphos-methyl is a broad spectrum organophosphate insecticide and potential toxic pollutant in aquatic ecosystems. The acute toxicity of Pirimiphos-methyl (Actellic) was investigated using Guppy (Poecilia reticulata) in a 96 h static renewal laboratory bioassay. Based on probit analysis the LC50
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