531677
m-Tolyl acetate
97%
Synonym(s):
3-Methylphenylacetate, m-Cresyl acetate, Acetic acid m-tolyl ester
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About This Item
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Quality Level
Assay
97%
refractive index
n20/D 1.501 (lit.)
bp
210-213 °C (lit.)
density
1.04 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
CC(=O)Oc1cccc(C)c1
InChI
1S/C9H10O2/c1-7-4-3-5-9(6-7)11-8(2)10/h3-6H,1-2H3
InChI key
OTGAHJPFNKQGAE-UHFFFAOYSA-N
General description
m-Tolyl acetate is an acyloxy benzene derivative that can be prepared from m-cresol and acetic anhydride.
Application
m-Tolyl acetate may be used in the preparation of 2-hydroxy-4-methylacetophenone and 4-hydroxy-2-methyl acetophenone via Fries rearrangement.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
203.0 °F - closed cup
Flash Point(C)
95 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis and characterization of o-hydroxyarylalkylketones by using eco-friendly solvent free catalyst in frie's rearrangement.
Der Pharma Chemica, 4(1), 377-382 (2012)
Effect of ketoconazole on external otitis.
Proceedings of the Western Pharmacology Society, 34, 351-352 (1991-01-01)
Systemic effects of endodontic intracanal medicaments, irrigants and sealers: danger on the bracket table.
Annals of dentistry, 44(1), 6-15 (1985-01-01)
Oral surgery, oral medicine, and oral pathology, 55(1), 91-94 (1983-01-01)
Four calcium hydroxide-based apexification pastes were tested for their antibacterial effects on Streptococcus sanguis. Their zones of growth inhibition on blood agar plates were measured at 2, 4, 6, and 8 days. Only the camphorated parachlorophenol and the metacresylacetate pastes
Quintessence international (Berlin, Germany : 1985), 28(6), 393-396 (1997-06-01)
The purpose of this study was to determine the effect of intracanal medicaments on the sealing ability of commonly used provisional filling materials. Ninety extracted, unrestored human molars were prepared. The contents of the pulp chamber were removed, and distal
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