528382
2-Methoxy-1-naphthoic acid
98%
Synonym(s):
2-Methoxynaphthoic acid
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About This Item
Linear Formula:
CH3OC10H6CO2H
CAS Number:
Molecular Weight:
202.21
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
mp
177-180 °C (lit.)
SMILES string
COc1ccc2ccccc2c1C(O)=O
InChI
1S/C12H10O3/c1-15-10-7-6-8-4-2-3-5-9(8)11(10)12(13)14/h2-7H,1H3,(H,13,14)
InChI key
OSTYZAHQVPMQHI-UHFFFAOYSA-N
General description
2-Methoxy-1-naphthoic acid is the 3-methoxy derivative of 1-napthoic acid. It can be prepared from a Grignard reagent derived from 1-bromo-2-methoxynaphthalene. 2-Methoxy-1-naphthoic acid undergoes Birch reduction to afford 2-methoxy-1,4,5,8-tetrahydro-1-naphthoic acid.
Application
2-Methoxy-1-naphthoic acid may be used in the synthesis of chiral (methoxynaphthyl)oxazoline.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Enantioselective synthesis of binaphthyls via nucleophilic aromatic substitution on chiral oxazolines.
Meyers AI and Lutomski KA.
Journal of the American Chemical Society, 104(3), 879-881 (1982)
Birch Reduction of 2-Naphthoic and of ortho-Methoxynaphthoic Acids.
Eliel EL and Hoover TE.
The Journal of Organic Chemistry, 24(7), 938-942 (1959)
The Reaction of Phenyl 2-Methoxy-1-naphthoate with Grignard Reagents. A New Route to Fluorenones.
Fuson RC and Wassmundt FW.
Journal of the American Chemical Society, 78(20), 5409-5413 (1956)
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