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T27006

Sigma-Aldrich

2-Thenoyltrifluoroacetone

99%

Synonym(s):

4,4,4-Trifluoro-1-(2-thienyl)-1,3-butanedione, TTA (extractant), TTB, TTFA

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About This Item

Empirical Formula (Hill Notation):
C8H5F3O2S
CAS Number:
326-91-0
Molecular Weight:
222.18
Beilstein:
168645
EC Number:
206-316-7
MDL number:
MFCD00005445
UNSPSC Code:
12352100
PubChem Substance ID:
24900067
NACRES:
NA.22

Assay

99%

bp

96-98 °C/8 mmHg (lit.)

mp

40-44 °C (lit.)

storage temp.

2-8°C

SMILES string

FC(F)(F)C(=O)CC(=O)c1cccs1

InChI

1S/C8H5F3O2S/c9-8(10,11)7(13)4-5(12)6-2-1-3-14-6/h1-3H,4H2

InChI key

TXBBUSUXYMIVOS-UHFFFAOYSA-N

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Application

Reagent for the determination of actinides and lanthanides.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

233.6 °F - closed cup

Flash Point(C)

112 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Vladimir A Kokorekin et al.
Molecules (Basel, Switzerland), 25(18) (2020-09-17)
In this article, we demonstrate how an original effective "metal-free" and "chromatography-free" route for the synthesis of 3-thiocyanatopyrazolo[1,5-a]pyrimidines has been developed. It is based on electrooxidative (anodic) C-H thiocyanation of 5-aminopyrazoles by thiocyanate ion leading to 4-thiocyanato-5-aminopyrazoles (stage 1, yields
Jeffery, G.H. et al.
Vogel's Textbook of Quantitative Chemical Analysis, 170-170 (1989)
David González-Aragón et al.
Biochemical pharmacology, 73(3), 427-439 (2006-11-25)
Dicoumarol, a competitive inhibitor of NAD(P)H:quinone oxidoreductase 1 (NQO1), increases intracellular superoxide and affects cell growth of tumor cells. This work was set to establish a mechanistic link between dicoumarol, superoxide and cell cycle alterations in HL-60 cells. Using ES936
Feng Gao et al.
Talanta, 80(1), 202-206 (2009-09-29)
Amino-functionalized luminescent silica nanoparticles (LSNPs) doped with the europium(III) mixed complex, Eu(TTA)(3)phen with 2-thenoyltrifluoroacetone (TTA) and 1,10-phenanthroline(phen) were synthesized successfully using an revised Stöber method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared (FTIR), and fluorescence spectroscopy were
Hiroko P Indo et al.
Mitochondrion, 7(1-2), 106-118 (2007-02-20)
Mitochondrial damage is a well known cause of mitochondria-related diseases. A major mechanism underlying the development of mitochondria-related diseases is thought to be an increase in intracellular oxidative stress produced by impairment of the mitochondrial electron transport chain (ETC). However
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