Skip to Content
Merck
All Photos(1)

Documents

750190

Sigma-Aldrich

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)

95%

Synonym(s):

Pd-117

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C36H28Cl2OP2Pd
CAS Number:
205319-06-8
Molecular Weight:
715.88
MDL number:
MFCD09953446
UNSPSC Code:
12352300
PubChem Substance ID:
329766057
NACRES:
NA.22

Assay

95%

form

powder

mp

243-250 °C

storage temp.

2-8°C

SMILES string

Cl[Pd]Cl.O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6

InChI

1S/C36H28OP2.2ClH.Pd/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32;;;/h1-28H;2*1H;/q;;;+2/p-2

InChI key

VYOUBMJFTDMKRR-UHFFFAOYSA-L

General description

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is a palladium(II) complex containing two chloride ligands and two (2-(diphenylphosphino)phenyl)ether ligands coordinated to the palladium center. It is used as a catalyst for the cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z, E dienes.

Application

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II) is used as an efficient catalyst in the coupling reaction.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Clean inversion of configuration in the Pd-catalyzed cross-coupling of 2-bromo-1, 3-dienes
Zeng X, et al.
Journal of the American Chemical Society, 125(45), 13636-13637 (2003)
For convenient trifluoromethylation of aryl iodides.
Trifluoromethylations H
Aldrichimica Acta, 2, 0-0 null

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service