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Assay
97%
form
solid
mp
288 °C (dec.) (lit.)
SMILES string
Cl[H].Cl[H].Cl[H].C1CNCCNCCN1
InChI
1S/C6H15N3.3ClH/c1-2-8-5-6-9-4-3-7-1;;;/h7-9H,1-6H2;3*1H
InChI key
HNPMVNQYFPWBKI-UHFFFAOYSA-N
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Application
1,4,7-Triazacyclononane trihydrochloride can be used as a reagent to prepare:
- Nonadentate ligand, 1,4,7-tris[(6-carboxypyridin-2-yl)methyl]-1,4,7-triazacyclononane (H3tpatcn), which is used to prepare lanthanide complexes with high water solubility and rigid C3 symmetric structures.
- Dansyl cryptands as fluorescent indicators via amination of (bromobenzyl)triazacycloalkane and oxadiamines.
- [1,4,7-tri(3-butenyl)-1,4,7-triazacyclononane and 1,4,7-tri(2-propenyl)-1,4,7-triazacyclononane] by reacting with corresponding alkenyl halide.
Possible reagent for compleximetric titrations with high cation-binding selectivity.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Solid-state and solution properties of the lanthanide complexes of a new nonadentate tripodal ligand derived from 1, 4, 7-triazacyclononane
Dalton Transactions, 2428-2433 (2003)
Synthesis of Dansyl-Substituted Cryptands Containing Triazacycloalkane Moieties and their Evaluation as Fluorescent Chemosensors
Synlett, 28(20), 2800-2806 (2017)
An investigation into alkenyl-functionalized 1, 4, 7-triazacyclononanes: Synthesis, metal complexation, and attempted olefin metathesis
Australian Journal of Chemistry, 55(10), 655-660 (2002)
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