298212
Copper(I) thiocyanate
99%
Synonym(s):
Cuprous thiocyanate
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All Photos(3)
About This Item
Linear Formula:
CuSCN
CAS Number:
Molecular Weight:
121.63
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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Assay
99%
form
powder
application(s)
battery manufacturing
SMILES string
[Cu]SC#N
InChI
1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1
InChI key
PDZKZMQQDCHTNF-UHFFFAOYSA-M
Related Categories
General description
The crystal belongs to the orthorhombic system, space group: Pbca,a=10.994(9)Å, b=7.224(3)Å,c=6.662(2)Å.
Application
The product can be prepared from Cu(CH3COO)2·H2O, AgNO3, NH4NCS and im(im = imidazole). The structure and optical properties were reported. It is an air- and light-stable source of Cu(I).
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Supplementary Hazards
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound
Bie HY, et al.
Journal of Molecular Structure, 660, 107-112 (2003)
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), (39)(39), 5290-5292 (2008-10-02)
The role of short-range diffusion in solvent-assisted mechanochemical synthesis is demonstrated in studies of a polymorphic transition and a ligand dissociation reaction involving copper(I) thiocyanate complexes.
S Bacon
Journal of human nutrition, 34(6), 445-449 (1980-12-01)
The advantages and disadvantages of faecal markers that are available in the UK are discussed. Opinions and comments from units using them are included.
The crystal structure of copper(I) thiocyanate and its relation to the crystal structure of copper(II) diammine dithiocyanate complex
Kabesova M, et al.
Inorgorganica Chimica Acta, 17, 161-165 (1976)
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), 41(25), 7513-7525 (2012-05-24)
A number of adducts of copper(I) thiocyanate with bulky tertiary phosphine ligands, and some nitrogen-base solvates, were synthesized and structurally and spectroscopically characterised. CuSCN:PCy3 (1:2), as crystallized from pyridine, is shown by a single crystal X-ray study to be a
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