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Quality Level
Assay
95%
bp
185 °C/135 mmHg (lit.)
mp
112-114 °C (lit.)
SMILES string
Brc1ccc-2c(Cc3ccccc-23)c1
InChI
1S/C13H9Br/c14-11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8H,7H2
InChI key
FXSCJZNMWILAJO-UHFFFAOYSA-N
General description
2-Bromofluorene is a nonintrusive end-capping reagent to control molecular weights and to generate well-defined oligomers.
Application
2-Bromofluorene was used in the synthesis of end-capping reagent 2-bromo-9,9-di-nhexylfluorene. It has been used in the preparation of poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene and 9-bromoanthracene through Ni(0) mediated polymerization. It was also used in the synthesis of 2-bromo-9,9-dihexylfluorene.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Find documentation for the products that you have recently purchased in the Document Library.
Polyfluorene derivatives: effective conjugation lengths from well-defined oligomers.
Macromolecules, 31(6), 2007-2009 (1998)
Tetrahedron Letters, 48, 89-89 (2007)
Tetrahedron Letters, 47, 7085-7085 (2006)
Excimer and Aggregate Formations in Poly (fluorene) s.
ETRI Journal, 24(6), 409-414 (2002)
Well-defined [3, 3'] bicarbazolyl-based electroactive compounds for optoelectronics.
Synthetic Metals, 158(8), 383-390 (2008)
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