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B79803

Sigma-Aldrich

3-Bromopropylamine hydrobromide

3-Bromopropylamine hydrobromide

98%

Synonym(s):

3-Aminopropyl bromide hydrobromide

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About This Item

Linear Formula:
BrCH2CH2CH2NH2 · HBr
CAS Number:
5003-71-4
Molecular Weight:
218.92
Beilstein:
3906418
EC Number:
225-675-0
MDL number:
MFCD00012912
UNSPSC Code:
12352100
PubChem Substance ID:
24892034
NACRES:
NA.22
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Quality Level

200

Assay

98%

form

crystals

mp

171-172 °C (lit.)

SMILES string

Br.NCCCBr

InChI

1S/C3H8BrN.BrH/c4-2-1-3-5;/h1-3,5H2;1H

InChI key

PQIYSSSTRHVOBW-UHFFFAOYSA-N

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Application

3-Bromopropylamine hydrobromide is commonly used as a reagent to introduce propylamine group to the molecular skeleton.[1][2][3] Some of the other reported applications include:
  • Synthesis of photochemically and thermally reactive azobenzene rotaxane[1] and indolocarbazole-containing [2]rotaxane.[4]
  • Synthesis of indenoisoquinoline based active topoisomerase I inhibitors as anticancer agents.[2][5]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000346578
0000346578
MKCW4913
0000243976
0000243976

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SYX00003

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Interlocked host anion recognition by an indolocarbazole-containing [2] rotaxane.
Brown A, et al.
Journal of the American Chemical Society, 131(13), 4937-4952 (2009)
Maya Juenet et al.
Biomaterials, 156, 204-216 (2017-12-08)
Injection of recombinant tissue plasminogen activator (rt-PA) is the standard drug treatment for thrombolysis. However, rt-PA shows risk of hemorrhages and limited efficiency even at high doses. Polysaccharide-poly(isobutylcyanoacrylate) nanoparticles functionalized with fucoidan and loaded with rt-PA were designed to accumulate
Optimization of the indenone ring of indenoisoquinoline topoisomerase I inhibitors.
Morrell A, et al.
Journal of Medicinal Chemistry, 50(18), 4388-4404 (2007)
Antagonist analogue of 6-[3 `-(1-adamantyl)-4 `-hydroxyphenyl]-2-naphthalenecarboxylic acid (AHPN) family of apoptosis inducers that effectively blocks AHPN-induced apoptosis but not cell-cycle arrest.
Dawson M I, et al.
Journal of Medicinal Chemistry, 47(14), 3518-3536 (2004)
Synthesis and anticancer activity of simplified indenoisoquinoline topoisomerase I inhibitors lacking substituents on the aromatic rings.
Nagarajan M, et al.
Journal of Medicinal Chemistry, 47(23), 5651-5661 (2004)
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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