Skip to Content
Merck
All Photos(3)

Key Documents

182265

Sigma-Aldrich

Poly(methyl methacrylate)

Synonym(s):

PMMA, Poly(methacrylic acid methyl ester)

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
[CH2C(CH3)(CO2CH3)]n
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

form

solid

Quality Level

autoignition temp.

580 °F

transition temp

Tg (DSC) 105 °C (midpoint)

solubility

H2O: insoluble

density

1.200 g/cm3

InChI

1S/C5H9O2/c1-4(2)5(6)7-3/h1-3H3

InChI key

PMAMJWJDBDSDHV-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Poly (methyl methacrylate) (PMMA) is an amorphous transparent thermoplastic polymer. PMMA is recognized as an optical polymer based on its refractive index of 1.49. Hence, it is used in optical fibers.[1]It finds uses in biological applications because of its low water absorption capability and biocompatible.The maximum moisture content of PMMA is 1.71% and SBF absorption is 1.96%.Simulated Body fluid test (SBF) is a method to characterize the in vitro bioactivity of ceramic materials, by immersing the materials in an aqueous SBF solution.

Application

PMMA/HA (Hydroxyapatite) composites have be used in biomedical applications such as dentistry, orthopedic retainers, and bone replacement. It has been used as substrate for graphene growth.[2]
Some studies report its use as
PMMA-titania hybrid optical thins films[1]
PMMA/polystryrene/clay nanocomposites[3]
PMMA/polyurethane/carbon black nanocomposites for methanol fuel cells.

Storage Class Code

11 - Combustible Solids

WGK

nwg

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Poly (methyl methacrylate) and polystyrene/clay nanocomposites prepared by in-situ polymerization.
Zeng C and Lee LJ
Macromolecules, 34(12), 4098-4103 (2001)
Jian-Chiun Liou et al.
Nanoscale research letters, 9(1), 1-1 (2014-01-02)
In this study, the Mo-electrode thin films were deposited by a two-stepped process, and the high-purity copper indium selenide-based powder (CuInSe2, CIS) was fabricated by hydrothermal process by Nanowin Technology Co. Ltd. From the X-ray pattern of the CIS precursor
High-refractive-index thin films prepared from trialkoxysilane-capped poly (methyl methacrylate)-titania materials
Lee LH, et al.
Chemistry of Materials, 13(3), 1137-1142 (2001)
A Fukushima et al.
Journal of dental research, 93(5), 525-529 (2014-02-21)
Corrosion of titanium is the major concern when it is used for dental treatment. This study aimed to investigate the mechanism of the microbiologically induced corrosive properties of titanium. An experimental well was made of polymethyl methacrylate with pure titanium
Bo Chen et al.
Journal of controlled release : official journal of the Controlled Release Society, 140(3), 203-209 (2009-05-26)
Water-soluble polymers for the delivery of chemotherapeutic drugs passively target solid tumors as a consequence of reduced renal clearance and the enhanced permeation and retention (EPR) effect. Elimination of the polymers in the kidney occurs due to filtration through biological

Articles

The detection and quantification of biomarkers are essential for medical diagnostics, environmental monitoring, and bioresearch.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

See All

Questions

1–5 of 5 Questions  
  1. What is the average size of PMMA beads, in product 182265, poly (methyl methacrylate)? (in nm or micrometre)? Are they 100 nm or 200 nm or 1 micrometre?

    1 answer
    1. Unfortunately, the product is not tested for particle size so there is no information that can be shared.

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. What are the alpha- and omega-ends of this PMMA?

    1 answer
    1. Unfortunately, the end group of 182265 (PMMA) is not tested.

      Helpful?

  5. What is the molecular weight of product 182265, poly (methyl methacrylate)?

    1 answer
    1. The average molecular weight for this product is 996,000 Daltons.

      Helpful?

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service