T45004

Triallylamine

99%

• Synonym(s): TAA
• Linear Formula: (H₂C=CHCH₂)₃N
• CAS Number: 102-70-5
• Molecular Weight: 137.22
• EC Number: 203-048-2
• MDL number: MFCD00026093
• UNSPSC Code: 12352100
• PubChem Substance ID: 24900211
• NACRES: NA.22

Properties

• vapor density: 4.73 (vs air)
• Quality Level: 200
• vapor pressure: 90 mmHg ( 80 °C)
• Assay: 99%
• refractive index: n20/D 1.451 (lit.)
• bp: 150-151 °C (lit.)
• density: 0.79 g/mL at 25 °C (lit.)
• SMILES string: C=CCN(CC=C)CC=C
• InChI: 1S/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2
• InChI key: VPYJNCGUESNPMV-UHFFFAOYSA-N

Description

Application

• Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
• TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
• The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.

Safety Information

• Pictograms: GHS02,GHS06,GHS05
• Signal Word: Danger
• Hazard Statements: H226,H302 + H312,H314,H331
• Precautionary Statements: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 87.8 °F - closed cup
• Flash Point(C): 31 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves