737321
Triphenylbismuth
98% (99.9% trace metals basis)
Synonym(s):
TPB
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About This Item
Linear Formula:
Bi(C6H5)3
CAS Number:
Molecular Weight:
440.29
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Pricing and availability is not currently available.
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Assay
98% (99.9% trace metals basis)
form
powder or crystals
reaction suitability
core: bismuth
availability
available only in USA
mp
76-81 °C
SMILES string
c1ccc(cc1)[Bi](c2ccccc2)c3ccccc3
InChI
1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;
InChI key
ZHXAZZQXWJJBHA-UHFFFAOYSA-N
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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O Anjaneyulu et al.
Dalton transactions (Cambridge, England : 2003), 41(3), 1004-1012 (2011-11-23)
The reaction of triphenylbismuth [BiPh(3)] with several heterocyclic carboxylic acids was explored. Seven crystalline compounds, [PhBi(2-O(2)C-3-(OH)C(5)H(3)N)(2)(2-O(2)C-3-(OH)C(5)H(3)NH)] (5), [(Bi(2-O(2)C-3-(OH)C(5)H(3)N)(4))(C(5)H(5)NH)(C(5)H(5)N)] (7), [PhBi(2-O(2)C-C(4)H(3)N(2))(2)(2-O(2)C-C(4)H(4)N(2))·H(2)O] (8), [PhBi(2-O(2)C-C(9)H(6)N)(2)·H(2)O] (9), [Ph(2)Bi(O(2)C-C(4)H(3)O)] (10), [Ph(2)Bi(O(2)C-C(4)H(3)S)] (11) and [PhBi(O(2)C-C(4)H(3)S)(2)](2) (12), were prepared by simple reactions using BiPh(3) and the corresponding
Brad H Jones et al.
Macromolecular rapid communications, 42(4), e2000571-e2000571 (2020-12-11)
This communication describes a novel series of linear and crosslinked polyurethanes (PUs) and their selective depolymerization under mild conditions. Two unique polyols are synthesized bearing unsaturated units in a configuration designed to favor ring-closing metathesis (RCM) to five- and six-membered
Hu Xu et al.
Journal of biomedical materials research. Part B, Applied biomaterials, 75(1), 64-73 (2005-07-15)
Radiopaque cement containing barium sulfate causes significantly more bone resorption in vivo and in vitro than radiolucent cement. The aim of this study was to investigate the osteolytic potential of an alternative radiopaque agent, triphenyl bismuth (TPB). Bone cement particles
S N Abdulghani et al.
Journal of biomaterials science. Polymer edition, 14(11), 1229-1242 (2004-02-11)
Self-curing acrylic bone cements are widely used in the fixation of prosthetic implants in orthopaedic surgery. Commercial bone cements are rendered radiopaque by the addition of heavy metal salts of barium and zirconia. The addition of barium sulphate adversely affects
P A Mattie et al.
Journal of prosthodontics : official journal of the American College of Prosthodontists, 3(4), 213-218 (1994-12-01)
Current prosthetic acrylic resins are radiolucent and cannot be imaged using standard radiographic techniques. If accidentally impacted or ingested, delays in localizing or removing the foreign body may be life-threatening. The purpose of this study was to evaluate the influence
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